Metal-Ion Intercalation Mechanisms in Vanadium Pentoxide and Its New Perspectives

被引：11

作者：

Alcantara, Ricardo ^{[1
]}

Lavela, Pedro ^{[1
]}

Edstroem, Kristina ^{[2
]}

Fichtner, Maximilian ^{[3
,4
]}

Le, Top Khac ^{[5
,6
]}

Floraki, Christina ^{[7
]}

Aivaliotis, Dimitris ^{[7
]}

Vernardou, Dimitra ^{[7
,8
]}

机构：

[1] Univ Cordoba, Dept Quim Inorgan Ingn Quim, Inst Quim Energia & Medioambiente IQEMA, Campus Rabanales,Edificio Marie Curie, E-14071 Cordoba, Spain

[2] Uppsala Univ, Dept Chem, Angstrom Lab, SE-75121 Uppsala, Sweden

[3] Karlsruhe Inst Technol, Inst Nanotechnol, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany

[4] Helmholtz Inst Ulm HIU Electrochem Energy Storage, Helmholtzstr 11, D-89081 Ulm, Germany

[5] Univ Sci, Fac Mat Sci & Technol, Ho Chi Minh City 700000, Vietnam

[6] Vietnam Natl Univ, Ho Chi Minh City 700000, Vietnam

[7] Hellen Mediterranean Univ, Sch Engn, Dept Elect & Comp Engn, Iraklion 71410, Greece

[8] Hellen Mediterranean Univ Ctr, Inst Emerging Technol, Iraklion 71410, Greece

来源：

NANOMATERIALS | 2023年 / 13卷 / 24期

关键词：

vanadium pentoxide; univalent ions; multivalent ions; dual-ion intercalation; cationic doping; electrolytes; interfaces; ENHANCED ELECTROCHEMICAL PROPERTIES; POSITIVE ELECTRODE MATERIALS; HIGH-RATE CAPABILITY; CATHODE MATERIAL; HIGH-PERFORMANCE; DOPED V2O5; SODIUM INSERTION; K-ION; CRYSTAL-STRUCTURE; LITHIUM;

D O I：

10.3390/nano13243149

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The investigation into intercalation mechanisms in vanadium pentoxide has garnered significant attention within the realm of research, primarily propelled by its remarkable theoretical capacity for energy storage. This comprehensive review delves into the latest advancements that have enriched our understanding of these intricate mechanisms. Notwithstanding its exceptional storage capacity, the compound grapples with challenges arising from inherent structural instability. Researchers are actively exploring avenues for improving electrodes, with a focus on innovative structures and the meticulous fine-tuning of particle properties. Within the scope of this review, we engage in a detailed discussion on the mechanistic intricacies involved in ion intercalation within the framework of vanadium pentoxide. Additionally, we explore recent breakthroughs in understanding its intercalation properties, aiming to refine the material's structure and morphology. These refinements are anticipated to pave the way for significantly enhanced performance in various energy storage applications.

引用

页数：28

共 116 条

[1] Investigation of the Na Intercalation Mechanism into Nanosized V2O5/C Composite Cathode Material for Na-Ion Batteries [J].