Novel ammonia-responsive carboxymethyl cellulose/Co-MOF multifunctional films for real-time visual monitoring of seafood freshness

Nowadays, ammonia-responsive biopolymer-based intelligent active films are of great interest for their huge potential in maintaining and monitoring the freshness of seafood. However, it is still a challenge to create biopolymer-based intelligent active films with favorable color stability, antibacterial and visual freshness indication functions. Herein, cobalt-based metal-organic framework (Co-MOF) nanosheets with ammonia-sensitive and antibacterial functions were successfully synthesized and then embedded into carboxymethyl cellulose (CMC) matrix to develop high performance and multifunctional CMC-based intelligent active films. The influence of Co-MOF addition on the structure, physical and functional characters of CMC film was comprehensively studied. The results showed that the Co-MOF nanofillers were homogeneously embedded within the CMC matrix, bringing about remarkable promotion on tensile strength (from 45.3 to 62.2 MPa), toughness (from 0.7 to 2.3 MJ/m3), water barrier and UV-blocking performance of CMC film. Notably, the obtained CMC/Co-MOF nanocomposite films also presented excellent long-term color stability, antibacterial activity (with the bacteriostatic efficiency of 99.6 % and 99.3 % against Escherichia coli and Staphylococcus aureus), and ammonia-sensitive discoloration performance. Finally, the CMC/Co-MOF nanocomposite films were successfully applied for realtime visual monitoring of shrimp freshness. The above results demonstrate that the CMC/Co-MOF nanocomposite films possess huge potential applications in intelligent active packaging.