A palladium(0)-threonine complex immobilized on the surface of magnetic mesocellular foam: an efficient, stable, and magnetically separable nanocatalyst for Suzuki, Stille, and Heck cross-coupling reactions

被引:3
|
作者
Shirvandi, Zeinab [1 ]
Ghorbani-Choghamarani, Arash [2 ]
Rostami, Amin [1 ]
机构
[1] Univ Kurdistan, Fac Sci, Dept Chem, Sanandaj 6617715175, Iran
[2] Bu Ali Sina Univ, Fac Chem, Dept Organ Chem, Hamadan 6517838683, Iran
关键词
CATALYTIC-ACTIVITY; HIGHLY EFFICIENT; PD NANOPARTICLES; PHOSPHINE-FREE; PALLADIUM NANOPARTICLES; HETEROGENEOUS CATALYST; REUSABLE CATALYST; ROOM-TEMPERATURE; ARYL CHLORIDES; MIZOROKI-HECK;
D O I
10.1039/d3ra02721j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this study, a new palladium nanocatalyst was supported on l-threonine functionalized magnetic mesocellular silica foams (MMCF@Thr-Pd) and was characterized by FT-IR, XRD, BET, SEM, EDS, VSM, TGA, ICP-OES and elemental mapping techniques. The obtained MMCF@Thr-Pd performance can show excellent catalytic activity for Stille, Suzuki, and Heck coupling reactions, and the corresponding products were obtained with high yields. More importantly, the efficient and stable MMCF@Thr-Pd nanocatalyst was recovered by applying an external magnetic field and reused for at least five consecutive runs without a change in the catalytic activity.
引用
收藏
页码:17449 / 17464
页数:16
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