A Green Approach of Utilising Banana Peel (Musa paradisiaca) as Adsorbent Precursor for an Anionic Dye Removal: Kinetic, Isotherm and Thermodynamics Analysis

被引:9
作者
Basirun, Ain Aqilah [1 ]
Othman, Ahmad Razi [2 ]
Yasid, Nur Adeela [1 ]
Abd Shukor, Mohd Yunus [1 ]
Khayat, Mohd Ezuan [1 ]
机构
[1] Univ Putra Malaysia UPM, Fac Biotechnol & Biomol Sci, Dept Biochem, Serdang 43400, Selangor, Malaysia
[2] Univ Kebangsaan Malaysia, Fac Engn & Built Environm, Dept Chem & Proc Engn, Bangi 43600, Selangor, Malaysia
关键词
biosorption; Evans blue dye; non-linear regression; thermodynamics; DILUTE AQUEOUS-SOLUTIONS; EVANS BLUE; ACTIVATED CARBON; WASTE-WATER; AGRICULTURAL WASTE; DURIAN SHELL; ADSORPTION; EQUILIBRIUM; BIOSORPTION; ELIMINATION;
D O I
10.3390/pr11061611
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Methods for removing pollutants include membrane isolation, ion exchange, precipitation, transformation, and biosorption. Adsorption is a cost-effective method of treating industrial wastewater and a common commercial method for concentrating valuable molecules or eliminating contaminants. Banana peel is one of the largest underutilized agricultural wastes in Malaysia. A novel method of using a low-cost biosorbent made from banana peel and Evans blue (EB) dye as a target is the target of this study. The optimal conditions for EB dye adsorption occurred at a dye concentration of 200 mg/L, adsorbent dosages between 10 and 20 g/L, temperature of 25 & DEG;C, incubation time of 180 min, and agitation speeds of 100 rpm. Statistical discriminatory analysis showed that the pseudo-second-order kinetic model and the Redlich-Petersen isotherm model were the best models. The maximum adsorption capacity based on Langmuir's isotherm prediction was 58.51 mg g(-1). A non-linear regression of the thermodynamic van't Hoff plot based on a dimensionless equilibrium constant resulted in negative values for Gibb's free energy and enthalpy, indicating that the adsorption process is spontaneous and exothermic.
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页数:22
相关论文
共 61 条
[1]  
Abdullah N., 2014, INT J BIOL VET AGR F, V8, P712
[2]   Adsorptive Removal of Malachite Green Dye Using Durian Seed-Based Activated Carbon [J].
Ahmad, Mohd Azmier ;
Ahmad, Norhidayah ;
Bello, Olugbenga Solomon .
WATER AIR AND SOIL POLLUTION, 2014, 225 (08)
[3]   Biosorption thermodynamic and kinetic of direct dye from aqueous solutions on bacterial cellulose [J].
Ashjaran, Ali ;
Yazdanshenas, Mohammad Esmail ;
Rashidi, Abosaeed ;
Khajavi, Ramin ;
Rezaee, Abbas .
AFRICAN JOURNAL OF MICROBIOLOGY RESEARCH, 2012, 6 (06) :1270-1278
[4]   Modelling and Interpretation of Adsorption Isotherms [J].
Ayawei, Nimibofa ;
Ebelegi, Augustus Newton ;
Wankasi, Donbebe .
JOURNAL OF CHEMISTRY, 2017, 2017
[5]   Biosorption of copper from aqueous solutions by date stones and palm-trees waste [J].
Belala, Zohra ;
Jeguirim, Mejdi ;
Belhachemi, Meriem ;
Addoun, Fatima ;
Trouve, Gwenaelle .
ENVIRONMENTAL CHEMISTRY LETTERS, 2011, 9 (01) :65-69
[6]   Application of cupuassu shell as biosorbent for the removal of textile dyes from aqueous solution [J].
Cardoso, Natali F. ;
Lima, Eder C. ;
Pinto, Isis S. ;
Amavisca, Camila V. ;
Royer, Betina ;
Pinto, Rodrigo B. ;
Alencar, Wagner S. ;
Pereira, Simone F. P. .
JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2011, 92 (04) :1237-1247
[7]   Evans blue removal from wastewater by rarasaponin-bentonite [J].
Chandra, I. K. ;
Ju, Y. -H. ;
Ayucitra, A. ;
Ismadji, S. .
INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY, 2013, 10 (02) :359-370
[8]   Adsorption of basic dye onto activated carbon prepared from durian shell: Studies of adsorption equilibrium and kinetics [J].
Chandra, Thio Christine ;
Mirna, M. M. ;
Sudaryanto, Y. ;
Ismadji, S. .
CHEMICAL ENGINEERING JOURNAL, 2007, 127 (1-3) :121-129
[9]  
Do D.D., 1998, ADSORPTION ANAL EQUI
[10]   Textural porosity, surface chemistry and adsorptive properties of durian shell derived activated carbon prepared by microwave assisted NaOH activation [J].
Foo, K. Y. ;
Hameed, B. H. .
CHEMICAL ENGINEERING JOURNAL, 2012, 187 :53-62