Molybdenum-Incorporated O3-type Sodium Layered Oxide Cathodes for High-Performance Sodium-Ion Batteries

Transition metal layered oxide materials with a general formula NaxMO2 (M = Ni, Mn, Co, Fe) are widely researched with various possible electrode configurations. Herein, O3-type NaNi(1-x)/2Mn(1-x)/2MoxO2 (x = 0, 0.05,0.1) layered oxide cathode materials are synthesized by solid-state reaction method, and its structural, thermal, and electrochemical performance in sodium ion battery is investigated. The structural analysis reveals that a single phase highly crystalline O3-type cathode material with an irregular particle shape is formed. The introduction of molybdenum improves the thermal stability of cathode materials, which can be attributed to the improved TMO2 layers that provide stability to the material. The addition of Mo to Na-layered oxide cathode materials enhances electrochemical performance. The developed cathode materials, the NaNi0.475Mn0.475Mo0.05O2, exhibit excellent specific discharge capacity (approximate to 154 mAh g-1) at C/20 rate, (an increase of approximate to 20% when compared to the NaNi0.5Mn0.5O2) which can be attributed to the increased capacitance effect by the addition of Mo. The electrochemical impedance spectroscopy study reveals that the diffusion of Na+ into/from the host structure is rapid during the first cycle and then gradually reduces with subsequent cycling due to the formation of the solid electrolyte interface layer, which hinders Na+ migration. This has a potential effect on the improved electrochemical performance of the material. The work presents an O3-type Na-layered oxide material incorporating molybdenum. A facile, green solid state method results in the synthesis of the Mo-containing NaNi(1-x)/2Mn(1-x)/2MoxO2 (x = 0, 0.05, 0.1) material. Structural characterizations confirm the phase of pure synthesis. The Mo-0.05 gives the best electrochemical performance with an achieved specific discharge capacity of approximate to 154 mAhg-1.image (c) 2023 WILEY-VCH GmbH