Comparative analysis of the aging kinetics in low-alloyed Cu-Cr-Hf and Cu-Cr-Zr alloys after high pressure torsion

被引:14
作者
Rybalchenko, O. V. [1 ]
Bochvar, N. R. [1 ]
Rybalchenko, G. V. [2 ]
Martynenko, N. S. [1 ]
Tabachkova, N. Yu. [3 ,4 ]
Dobatkin, S. V. [1 ,3 ]
机构
[1] Russian Acad Sci, A A Baikov Inst Met & Mat Sci, Leninsky Prospect,49, Moscow 119334, Russia
[2] Russian Acad Sci, P N Lebedev Phys Inst, Leninsky Prospect,53, Moscow 119334, Russia
[3] Natl Univ Sci & Technol MISIS, Leninsky prospect,4, Moscow 119049, Russia
[4] Russian Acad Sci, A M Prokhorov Gen Phys Inst, Vavilov Str,38, Moscow 119333, Russia
关键词
Cu; Cr; Hf and Cu; Zr alloys; High pressure torsion; Phase precipitation; Thermal analysis; Microhardness; Electrical properties; HEAT-TREATMENT; PRECIPITATION; MICROSTRUCTURE; ZIRCONIUM; BEHAVIOR; CONDUCTIVITY; MECHANISMS; CORROSION;
D O I
10.1016/j.jallcom.2023.170246
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The kinetics of phase precipitation during aging in the Cu - Cr - Hf and Cu - Cr - Zr alloys after high pressure torsion (HPT) has been studied and compared with quenching state. The effect of HPT on the kinetics of aging was revealed by the differential scanning calorimetry (DSC) and confirmed by changes in the microhardness and electrical resistivity. Analysis of the microstructure and phase precipitation after HPT and subsequent aging using a transmission electron microscopy (TEM) and energy dispersive spec-troscopy (EDS) revealed three types of phases in each of the alloys: Cu matrix, chromium and zirconium-or hafnium-rich phases. By measuring the microhardness, a higher degree hardening after HPT and subsequent aging was revealed in the Cu - Cr - Hf alloy compared to the Cu - Cr - Zr alloy.(c) 2023 Elsevier B.V. All rights reserved.
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页数:9
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