Comprehensive overview of polyoxometalates for electrocatalytic hydrogen evolution reaction

被引：119

作者：

Zeb, Zonish ^{[1
]}

Huang, Yichao ^{[1
,2
]}

Chen, Lulu ^{[2
]}

Zhou, Wenbo ^{[2
]}

Liao, Meihong ^{[3
]}

Jiang, Yangyang ^{[2
]}

Li, Haitao ^{[2
]}

Wang, Limin ^{[2
]}

Wang, Lin ^{[2
]}

Wang, Hang ^{[2
]}

Wei, Tong ^{[2
]}

Zang, Dejin ^{[1
,4
]}

Fan, Zhuangjun ^{[2
]}

Wei, Yongge ^{[1
]}

机构：

[1] Tsinghua Univ, Minist Educ, Dept Chem, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China

[2] China Univ Petr, Sch Mat Sci & Engn, State Key Lab Heavy Oil Proc, Qingdao 266580, Peoples R China

[3] Qingdao Binhai Univ, Sch Mech & Elect Engn, Qingdao 266555, Shandong, Peoples R China

[4] Shandong First Med Univ & Shandong Acad Med Sci, Inst Mat Med, Jinan 250117, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2023年 / 482卷

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

Polyoxometalates; Transition metals; Electrocatalysts; Hydrogen evolution reaction; Water splitting; HIGHLY-ACTIVE ELECTROCATALYSTS; METAL-ORGANIC FRAMEWORKS; MOLYBDENUM CARBIDE NANOPARTICLES; REDUCED GRAPHENE OXIDE; CARBON-FIBER PAPER; EFFICIENT ELECTROCATALYST; DOPED CARBON; HIGH-PERFORMANCE; BIFUNCTIONAL ELECTROCATALYST; RECENT PROGRESS;

D O I：

10.1016/j.ccr.2023.215058

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electrocatalytic water splitting via hydrogen evolution reaction (HER) from renewable energy sources is an attractive alternative to produce hydrogen, but it still encounters the limitations of large-scale appli-cability of Pt-based electrocatalysts. Therefore, abundant efforts have been devoted to design and fabri-cate highly efficient and stable noble-metal-free electrocatalysts to replace the expensive Pt-based electrocatalysts. Recently, polyoxometalates (POMs) and their derivatives have been proven to provide plentiful opportunities for designing and fabricating highly efficient and stable noble-metal-free HER electrocatalysts with controllable catalytic active sites and well-defined nanostructures. In this review, recent advances on coordination structures and HER performances of POMs-contained composites and POMs-derived transition metal carbides, chalcogenides, phosphides, nitrides and other electrocatalysts have been discussed.(c) 2023 Elsevier B.V. All rights reserved.

引用

页数：53