Progress in Isocyanide-Based Step-Growth Polymerization

被引：5
作者：
Li, Mingzhao [1 ,2 ]
Fu, Xinyao [1 ,2 ]
Wang, Jia [1 ,2 ]
Qin, Anjun [1 ,2 ]
Tang, Ben Zhong [2 ,3 ]
机构：
[1] South China Univ Technol, AIE Inst, Guangdong Prov Key Lab Luminescence Mol Aggregates, Ctr Aggregat Induced Emiss,State Key Lab Luminesce, Guangzhou 510640, Peoples R China
[2] South China Univ Technol, AIE Inst, Ctr Aggregat Induced Emiss, Guangzhou 510640, Peoples R China
[3] Chinese Univ Hong Kong, Shenzhen Inst Aggregate Sci & Technol, Sch Sci & Engn, Shenzhen 518172, Peoples R China
来源：
MACROMOLECULAR CHEMISTRY AND PHYSICS | 2023年 / 224卷 / 03期
基金：
中国国家自然科学基金;
关键词：
functional polymers; isocyanide; multicomponent polymerization; step-growth polymerization; PASSERINI MULTICOMPONENT POLYMERIZATION; ONE-POT SYNTHESIS; FACILE SYNTHESIS; UGI-REACTION; DIALKYLACETYLENE DICARBOXYLATES; 3-COMPONENT POLYMERIZATION; SEQUENCE CONTROL; CARBON-DIOXIDE; SIDE-CHAIN; POLYAMIDES;
D O I：
10.1002/macp.202200352
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Isocyanide is an important class of active synthon with a special electronic structure and abundant chemical properties, which can participate in various organic reactions and has a wide range of applications in the efficient synthesis of pharmaceutical molecules, heterocyclic compounds, and natural products, etc. With the development of chemical science, isocyanide-based reactions have been gradually applied from the synthesis of low mass molecules to functional polymers. This review focuses on the recent progress in isocyanide-based step-growth polymerization, as well as the properties and applications of the resultant functional polymers. These polymerizations are divided into six main parts including Passerini polymerization, Ugi polymerization, multicomponent polymerization (MCP) of isocyanide and dialkylacetylenedicarboxylates (DAADs), MCP of isocyanide and green monomer, MCP of isocyanide and industrial waste, as well as the polymerization based on isocyanoacetate. The existing challenges and the promising opportunities are concisely discussed.
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页数：18
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