Dielectric relaxation and hydrogen bonding studies of chlorobutane-dioxane mixtures using a time domain technique

被引：5

作者：

Gubre, A. G. ^{[1
]}

Kumbharkhane, A. C. ^{[1
]}

机构：

[1] SRTM Univ, Sch Phys Sci, Nanded 431606, MS, India

来源：

JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2023年 / 100卷 / 06期

关键词：

Time domain reflectometry (TDR); Complex permittivity spectra; Static dielectric constant; Relaxation time; Kirkwood correlation factor and Bruggeman; factor; N-HEXANE;

D O I：

10.1016/j.jics.2023.101016

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complex permittivity spectra have been computed for the binary mixtures of Chlorobutane (CLB) with 1, 4-Dioxane (DX) using Time Domain Reflectometry (TDR) for different concentrations and temperatures in the frequency range from 10 MHz to 30 GHz. The static dielectric permittivity and relaxation time have been ob-tained by fitting complex permittivity spectra to the Debye relaxation using least squares fit method. The Kirkwood correlation factor have been determined at various concentrations of 1, 4-dioxane. The Bruggeman model for the non-linear case has been fitted to the dielectric data for the mixtures.

引用

页数：5

共 15 条

[1] Refractive indices and static permittivities of systems containing n-hexane or n-heptane and isomeric chlorobutanes [J].