Researchers studying heterogeneous catalysis are intrigued by single-atom catalysts (SACs) due to their ultrahigh atomic utilization. However, only a few reports on SAC-catalyzed classical organic transformations are available. In this work, atomically dispersed Pd sites are confined to a ZrO2 hybridized N-doped carbon skeleton with a smart design. UiO-66-NH2 is used to anchor Pd atoms by the coordination of the donor atoms including lone pairs of electrons and metal atoms. Subsequently, the in situ introduction of ZrO2 doping is achieved using pyrolysis, which helps improve the catalytic performance by modulating the electronic state. The Pd@ZrO2/N-C catalyst obtained from the unique design exhibits a high yield (99%) in eco-friendly media with an extremely low noble metal dosage (0.03 mol% Pd) for the Suzuki reaction. Moreover, Pd@ZrO2/N-C remains highly active after being reused several times and possesses versatility in a variety of substrates. This strategy offers a feasible alternative to designing SACs with atomically dispersed noble metals for heterogeneous reactions.
机构:
Lanzhou Univ, Coll Chem & Chem Engn, Lab Special Funct Mat & Struct Design, State Key Lab Appl Organ Chem,Minist Educ, Lanzhou 730000, Peoples R ChinaLanzhou Univ, Coll Chem & Chem Engn, Lab Special Funct Mat & Struct Design, State Key Lab Appl Organ Chem,Minist Educ, Lanzhou 730000, Peoples R China
Li, Boyang
Kou, Jinfang
论文数: 0引用数: 0
h-index: 0
机构:
Lanzhou Univ, Coll Chem & Chem Engn, Lab Special Funct Mat & Struct Design, State Key Lab Appl Organ Chem,Minist Educ, Lanzhou 730000, Peoples R ChinaLanzhou Univ, Coll Chem & Chem Engn, Lab Special Funct Mat & Struct Design, State Key Lab Appl Organ Chem,Minist Educ, Lanzhou 730000, Peoples R China
Kou, Jinfang
Zeng, Gong
论文数: 0引用数: 0
h-index: 0
机构:
Lanzhou Univ, Coll Chem & Chem Engn, Lab Special Funct Mat & Struct Design, State Key Lab Appl Organ Chem,Minist Educ, Lanzhou 730000, Peoples R ChinaLanzhou Univ, Coll Chem & Chem Engn, Lab Special Funct Mat & Struct Design, State Key Lab Appl Organ Chem,Minist Educ, Lanzhou 730000, Peoples R China
Zeng, Gong
Ma, Jiantai
论文数: 0引用数: 0
h-index: 0
机构:
Lanzhou Univ, Coll Chem & Chem Engn, Lab Special Funct Mat & Struct Design, State Key Lab Appl Organ Chem,Minist Educ, Lanzhou 730000, Peoples R ChinaLanzhou Univ, Coll Chem & Chem Engn, Lab Special Funct Mat & Struct Design, State Key Lab Appl Organ Chem,Minist Educ, Lanzhou 730000, Peoples R China
Ma, Jiantai
Dong, Zhengping
论文数: 0引用数: 0
h-index: 0
机构:
Lanzhou Univ, Coll Chem & Chem Engn, Lab Special Funct Mat & Struct Design, State Key Lab Appl Organ Chem,Minist Educ, Lanzhou 730000, Peoples R ChinaLanzhou Univ, Coll Chem & Chem Engn, Lab Special Funct Mat & Struct Design, State Key Lab Appl Organ Chem,Minist Educ, Lanzhou 730000, Peoples R China
机构:
Korea Univ, KU KIST Grad Sch Converging Sci & Technol, 145 Anam Ro, Seoul 02841, South KoreaKorea Univ, KU KIST Grad Sch Converging Sci & Technol, 145 Anam Ro, Seoul 02841, South Korea
Shin, Hyeon Ho
Kang, Eunmi
论文数: 0引用数: 0
h-index: 0
机构:
Korea Univ, KU KIST Grad Sch Converging Sci & Technol, 145 Anam Ro, Seoul 02841, South KoreaKorea Univ, KU KIST Grad Sch Converging Sci & Technol, 145 Anam Ro, Seoul 02841, South Korea
Kang, Eunmi
Park, Haeli
论文数: 0引用数: 0
h-index: 0
机构:
Korea Univ, KU KIST Grad Sch Converging Sci & Technol, 145 Anam Ro, Seoul 02841, South KoreaKorea Univ, KU KIST Grad Sch Converging Sci & Technol, 145 Anam Ro, Seoul 02841, South Korea
Park, Haeli
Han, Taejun
论文数: 0引用数: 0
h-index: 0
机构:
Korea Univ, KU KIST Grad Sch Converging Sci & Technol, 145 Anam Ro, Seoul 02841, South KoreaKorea Univ, KU KIST Grad Sch Converging Sci & Technol, 145 Anam Ro, Seoul 02841, South Korea
Han, Taejun
Lee, Chul-Ho
论文数: 0引用数: 0
h-index: 0
机构:
Korea Univ, KU KIST Grad Sch Converging Sci & Technol, 145 Anam Ro, Seoul 02841, South KoreaKorea Univ, KU KIST Grad Sch Converging Sci & Technol, 145 Anam Ro, Seoul 02841, South Korea
Lee, Chul-Ho
Lim, Dong-Kwon
论文数: 0引用数: 0
h-index: 0
机构:
Korea Univ, KU KIST Grad Sch Converging Sci & Technol, 145 Anam Ro, Seoul 02841, South KoreaKorea Univ, KU KIST Grad Sch Converging Sci & Technol, 145 Anam Ro, Seoul 02841, South Korea
机构:
Nanjing Normal Univ, Sch Chem & Mat Sci, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Peoples R ChinaNanjing Normal Univ, Sch Chem & Mat Sci, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Peoples R China
Lin, Zinan
Yang, Anzhou
论文数: 0引用数: 0
h-index: 0
机构:
Nanjing Normal Univ, Sch Chem & Mat Sci, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Peoples R ChinaNanjing Normal Univ, Sch Chem & Mat Sci, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Peoples R China
Yang, Anzhou
Zhang, Binbin
论文数: 0引用数: 0
h-index: 0
机构:
Nanjing Normal Univ, Sch Chem & Mat Sci, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Peoples R ChinaNanjing Normal Univ, Sch Chem & Mat Sci, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Peoples R China
Zhang, Binbin
Liu, Bing
论文数: 0引用数: 0
h-index: 0
机构:
Jiangnan Univ, Sch Chem & Mat Engn, Dept Chem Engn, Wuxi 214122, Jiangsu, Peoples R ChinaNanjing Normal Univ, Sch Chem & Mat Sci, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Peoples R China
Liu, Bing
Zhu, Jiawei
论文数: 0引用数: 0
h-index: 0
机构:
Jiangnan Univ, Sch Chem & Mat Engn, Dept Chem Engn, Wuxi 214122, Jiangsu, Peoples R ChinaNanjing Normal Univ, Sch Chem & Mat Sci, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Peoples R China
Zhu, Jiawei
Tang, Yawen
论文数: 0引用数: 0
h-index: 0
机构:
Nanjing Normal Univ, Sch Chem & Mat Sci, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Peoples R ChinaNanjing Normal Univ, Sch Chem & Mat Sci, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Peoples R China
Tang, Yawen
Qiu, Xiaoyu
论文数: 0引用数: 0
h-index: 0
机构:
Nanjing Normal Univ, Sch Chem & Mat Sci, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Peoples R ChinaNanjing Normal Univ, Sch Chem & Mat Sci, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Peoples R China