Analyzing porosity of compacted bentonite via through diffusion method

被引:2
作者
Feng, Zhengye [1 ]
Tian, Junlei [1 ]
Shi, Xiaoqiong [1 ]
Wang, Chao [1 ]
Wu, Tao [1 ]
机构
[1] Huzhou Univ, Dept Engn, Huzhou 313000, Peoples R China
关键词
Effective diffusion coefficient; Diffuse double-layer; Bentonite; Multi-porosity model; Through-diffusion experiment; RE(VII) DIFFUSION; TRACER DIFFUSION; ANION-EXCLUSION; ADSORPTION; POREWATER; SE(IV); HTO; MONTMORILLONITE; COEFFICIENTS; CL-36(-);
D O I
10.1007/s10967-024-09368-y
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The diffusion behavior of ReO4- (as a surrogate for 99TcO4-) and HSeO3- (as a surrogate for 79HSeO3-) in compacted Wyoming bentonite was investigated. A through-diffusion experiment was conducted to measure the effective diffusion coefficient and the accessible porosity at high salinity. Two multi-porosity models (MP1 and MP2) were employed to analyze the effect of compaction on the accessible porosity, the diffuse double-layer porosity, and the interlayer porosity. The diffuse double-layer porosity increased with increasing the external surface area.
引用
收藏
页码:1185 / 1193
页数:9
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