The corrosion behavior of various CVD SiC coatings in molten silicon

被引:6
作者
Berdoyes, I. [1 ]
Plaisantin, H. [1 ,2 ]
Danet, J. [1 ]
Lepetitcorps, Y. [1 ]
Roger, J. [1 ]
机构
[1] Univ Bordeaux, Lab Compos Thermostructuraux, Safran Ceram, CNRS,CEA, 3 Allee Boetie, F-33600 Pessac, France
[2] Safran Ceram, 105 Ave Marcel Dassault, F-33700 Merignac, France
关键词
B; Composites; B. Electron microscopy; C; Corrosion; D; SiC; MATRIX COMPOSITES; CARBIDE; MICROSTRUCTURE; MECHANISMS; HYDROGEN;
D O I
10.1016/j.ceramint.2023.11.147
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Corrosion by molten silicon of different SiC CVD coatings has been investigated at 1450 degrees C and 1550 degrees C by analyzing the deteriorated zone with electron microscopies. The influence of the microstructure on the corrosion mode is finely considered. The most resistant material consists of wide and aligned <111> oriented columns, perpendicular to the substrate, corresponding to an arrangement of dense {111} planes parallel to the surface in contact with the molten silicon. Structural disorder (grain boundaries, structural defects) and disorientations (growth direction other than <111>, secondary growth, column misalignment) make the CVD SiC coating more vulnerable to corrosion.
引用
收藏
页码:3877 / 3886
页数:10
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