Study of Application of Layered Double Hydroxide Derived from Zinc-Plating Wastewater to Boron Adsorbent

被引：0

作者：

Enomoto, Daisuke ^{[1
]}

Takuma, Yasuhiko ^{[1
]}

Morikubo, Satoshi ^{[1
]}

Yanagida, Sayaka ^{[1
]}

Kosaka, Yukio ^{[1
]}

机构：

[1] Tokyo Metropolitan Ind Technol Res Inst, 2-4-10 Aomi,Koto Ku, Tokyo 1350064, Japan

来源：

KAGAKU KOGAKU RONBUNSHU | 2023年 / 49卷 / 06期

关键词：

Zinc-Plating; Boron; Plating Wastewater; Wastewater Treatment; Layered Double Hydroxide; HYDROTALCITE-LIKE; REMOVAL; CARBONATE; SULFATE; BORATE;

D O I：

10.1252/kakoronbunshu.49.184

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Layered double hydroxides (LDH) were synthesized from zinc-plating wastewater and its applicability to boron adsorbent was investigated. Since the high concentration of sulfate ions in zinc-plating wastewater is assumed to inhibit the boron adsorption capacity, we searched for optimal synthesis conditions using simulated wastewater with sulfate ions added. It was suggested that the boron adsorption capacity of LDH decreases when large amounts of sulfate ions are present in wastewater. However, in case carbonated-LDH was synthesized with sodium carbonate and the interlayer carbonate ions were removed by calcination at 450 degrees C, oxidized LDH (LDO) was obtained, and the amount of sulfate ion contained in LDO was reduced, thereby boron adsorption capacity was improved. LDO obtained by calcination at 450 degrees C had the same boron adsorption capacity as that of the simulated wastewater, even when using zinc-plating wastewater, so the influence of foreign substances other than sulfate ions was negligible. Therefore, this study is expected to be an effective method of utilizing zinc-plating wastewater.

引用

页码：184 / 190

页数：7

共 21 条

[1] Boron removal by hydrotalcite-like, carbonate-free Mg-Al-NO73-LDH and a rationale on the mechanism [J].

Ay, Ahmet Nedim ;

Zuemreoglu-Karan, Birguel ;

Temel, Abidin .

MICROPOROUS AND MESOPOROUS MATERIALS, 2007, 98 (1-3) :1-5

[2] Zn-Al-based layered double hydroxides (LDH) active structures for dental restorative materials [J].

Bernardo, Marcela Piassi ;

Ribeiro, Caue .

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, 2019, 8 (01) :1250-1257

[3] An updated review on boron removal from water through adsorption processes [J].

Bhagyaraj, Sneha ;

Al-Ghouti, Mohammad A. ;

Kasak, Peter ;

Krupa, Igor .

EMERGENT MATERIALS, 2021, 4 (05) :1167-1186

[4] Influence of calcination on the adsorptive removal of phosphate by Zn-Al layered double hydroxides from excess sludge liquor [J].

Cheng, Xiang ;

Huang, Xinrui ;

Wang, Xingzu ;

Sun, Dezhi .

JOURNAL OF HAZARDOUS MATERIALS, 2010, 177 (1-3) :516-523

[5]

Hibino T., 2006, J CLAY SCI SOC JAPAN, V45, P102

[6]

Kaida Y., 2003, Mizu Kankyo Gakkaishi, V26, P843

[7]

Koga H., 2015, J. Surf. Finish. Soc. Jpn., V66, P76

[8] High Sorptive Removal of Borate from Aqueous Solution Using Calcined ZnAl Layered Double Hydroxides [J].

Koilraj, Paulmanickam ;

Srinivasan, Kannan .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (11) :6943-6951

[9] Coagulation-sedimentation method using aluminum sulfate and calcium hydroxide for removal of boric acid from wastewater - Improvement of removal rate of boric acid by addition of gypsum into wastewater [J].

Kudo, S ;

Sakata, M .

NIPPON KAGAKU KAISHI, 2002, (02) :265-268

[10] A novel conversion process for waste slag: synthesis of a hydrotalcite-like compound and zeolite from blast furnace slag and evaluation of adsorption capacities [J].

Kuwahara, Yasutaka ;

Ohmichi, Tetsutaro ;

Kamegawa, Takashi ;

Mori, Kohsuke ;

Yamashita, Hiromi .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (24) :5052-5062

← 1 2 3 →