Multiscale Imaging Techniques for Real-Time, Noninvasive Diagnosis of Li-Ion Battery Failures

With the increasing popularity of battery-powered mobility, ensuring the safety and reliability of Li-ion batteries (LIBs) has become critical for manufacturers. Despite advanced manufacturing processes for large-scale Li-ion cells, "latent defects" still unintentionally appear, due to imbalanced battery design, invisible faults, and extreme operating conditions. These defects cause performance degradation and can even lead to battery fires. Hence, early detection of latent defects, along with understanding the influence of cell parameters and operating conditions on battery failure scenarios, is crucial. For straightforward investigations and interpretations, noninvasive and in operando battery imaging techniques and methods have been proposed using X-rays, neutrons, and ultrasound, as these can penetrate active and component materials and cell packaging. Moreover, magnetic-field-guided visualization of the current distribution pattern in cells under a current load has been proposed to identify invisible defects. This review thoroughly examines various imaging techniques for internal batteries, from the atomic and molecular levels in electrode materials and interfaces to macroscale battery systems. By assessing qualitative case studies and newly discovered phenomena, this review provides valuable insights into state-of-the-art noninvasive battery imaging and its potential to improve the safety and reliability of LIB technology. Diagnosing Li secondary batteries using in operando, noninvasive imaging tools is crucial for securing their safety and reliability. Combining X-rays, neutrons, ultrasound, and magnetic fields, multiscale battery imaging through its hierarchy from particle to cell level can provide a comprehensive picture of the structural and chemical information of the battery interior, aiding in understanding various failure scenarios and pinpointing the defect locations.image (c) 2023 WILEY-VCH GmbH