Novel heteroligand Ni(II) complexes with benzylmalonate dianions: synthesis, structure, and thermal behavior

被引：0
作者：
Matiukhina, Anna K. [1 ]
Chistyakov, Aleksandr S. [1 ]
Zorina-Tikhonova, Ekaterina N. [1 ]
Gogoleva, Natalia V. [1 ]
Vologzhanina, Anna V. [2 ]
Kiskin, Mikhail A. [1 ]
Eremenko, Igor L. [1 ,2 ]
机构：
[1] Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, Moscow, Russia
[2] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow, Russia
来源：
MONATSHEFTE FUR CHEMIE | 2023年 / 154卷 / 10期
基金：
俄罗斯科学基金会;
关键词：
Nickel(II); Dicarboxylic acid; Substituted malonates; Crystal structure; Thermal decomposition; Coordination chemistry; TETRAAZA MACROCYCLIC COMPLEXES; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; CO-II; MAGNETIC-PROPERTIES; MALONATE ANIONS; NICKEL(II); COBALT(II); METAL; NI;
D O I：
10.1007/s00706-023-03114-y
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The two het e roligand Ni( II) complexes were synthesized: tet ranuclear ionic complex (NBu4)4[Ni4(OH)2(Bzmal)4(H2O)6]-(OAc) 2 center dot 8H2O and mononuclear neutral complex [Ni(Bzmal)2(4-ampyH)2]. 2H2O center dot 2DMF (where NBu4 + is the tetrabutylammonium cation, Bzmal2- are benzylmalonate dianions, and 4-ampyH+ is the 4-(ammoniummethyl)pyridine). The structure of the complexes was determined by single- crystal X- ray diffraction analysis. The simultaneous thermal analysis of [Ni(Bzmal)2(4-ampyH)2] center dot 2H2O center dot 2DMF was performed. [GRAPHICS] .
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收藏
页码：1137 / 1144
页数：8
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