Novel heteroligand Ni(II) complexes with benzylmalonate dianions: synthesis, structure, and thermal behavior

被引：0

作者：

Matiukhina, Anna K. ^{[1
]}

Chistyakov, Aleksandr S. ^{[1
]}

Zorina-Tikhonova, Ekaterina N. ^{[1
]}

Gogoleva, Natalia V. ^{[1
]}

Vologzhanina, Anna V. ^{[2
]}

Kiskin, Mikhail A. ^{[1
]}

Eremenko, Igor L. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, Moscow, Russia

[2] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow, Russia

来源：

MONATSHEFTE FUR CHEMIE | 2023年 / 154卷 / 10期

基金：

俄罗斯科学基金会;

关键词：

Nickel(II); Dicarboxylic acid; Substituted malonates; Crystal structure; Thermal decomposition; Coordination chemistry; TETRAAZA MACROCYCLIC COMPLEXES; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; CO-II; MAGNETIC-PROPERTIES; MALONATE ANIONS; NICKEL(II); COBALT(II); METAL; NI;

D O I：

10.1007/s00706-023-03114-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The two het e roligand Ni( II) complexes were synthesized: tet ranuclear ionic complex (NBu4)4[Ni4(OH)2(Bzmal)4(H2O)6]-(OAc) 2 center dot 8H2O and mononuclear neutral complex [Ni(Bzmal)2(4-ampyH)2]. 2H2O center dot 2DMF (where NBu4 + is the tetrabutylammonium cation, Bzmal2- are benzylmalonate dianions, and 4-ampyH+ is the 4-(ammoniummethyl)pyridine). The structure of the complexes was determined by single- crystal X- ray diffraction analysis. The simultaneous thermal analysis of [Ni(Bzmal)2(4-ampyH)2] center dot 2H2O center dot 2DMF was performed. [GRAPHICS] .

引用

页码：1137 / 1144

页数：8

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