Osteoconductive element-doped, porous, and low-elastic-modulus duplex coatings on a Ti-6Al-4 V alloy: A hybrid coating system for accelerating cell growth

被引:27
作者
Arun, S. [1 ,2 ]
Lim, Beyong-Seok [1 ,2 ]
Ahn, Sang -Gun [3 ]
Choe, Han-Cheol [1 ,2 ]
机构
[1] Chosun Univ, Dept Dent Mat, Adv Funct Surface & Biomat Res Lab, Gwangju 61452, South Korea
[2] Chosun Univ, Coll Dent, Res Ctr Surface Control Oral Tissue Regenerat, BRL Ctr NRF, Gwangju 61452, South Korea
[3] Chosun Univ, Coll Dent, Dept Pathol, Gwangju 61452, South Korea
基金
新加坡国家研究基金会;
关键词
Plasma oxidation process; Radiofrequency magnetron sputtering; Duplex treatment; PLASMA ELECTROLYTIC OXIDATION; MICRO-ARC OXIDATION; MECHANICAL-PROPERTIES; CORROSION BEHAVIOR; ELECTROPHORETIC DEPOSITION; SURFACE-MORPHOLOGY; CALCIUM-PHOSPHATE; TITANIUM-ALLOY; TIO2; MICROSTRUCTURE;
D O I
10.1016/j.jallcom.2023.169131
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Here, porous, hydrophilic, and low-elastic-modulus bioactive coatings were fabricated on a Ti-6Al-4 V alloy by a duplex treatment of plasma electrolytic oxidation (PEO), followed by radiofrequency magnetron sputtering (RF-MS). The PEO oxide layer was doped with an osteoconductive bioinorganic element, Zn, to enhance its biological performance. Detailed morphological, chemical, and phase analyses were performed on the coatings. The TiO2/hydroxyapatite coatings exhibited excellent hydrophilicity, owing to their porous morphology. A high defect density was induced under high process conditions. Porous columnar growth was observed on the Zn layer. MC3T3-E1 cell studies indicated that minimal Zn concentrations promoted high cell proliferation.(c) 2023 Elsevier B.V. All rights reserved.
引用
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页数:21
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