共 81 条
Exploring the synthesis, structure, and optoelectronic properties of lead-free halide perovskite Cs3Bi2I9 in single crystal and polycrystalline forms
被引:3
作者:

Sujith, P.
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Natl Inst Technol Goa, Dept Appl Sci, Ponda 403401, Goa, India Natl Inst Technol Goa, Dept Appl Sci, Ponda 403401, Goa, India

Parne, Saidi Reddy
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Natl Inst Technol Goa, Dept Appl Sci, Ponda 403401, Goa, India Natl Inst Technol Goa, Dept Appl Sci, Ponda 403401, Goa, India

Abhinav, T.
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Natl Inst Technol, Dept Phys, Calicut 673601, Kerala, India Natl Inst Technol Goa, Dept Appl Sci, Ponda 403401, Goa, India
机构:
[1] Natl Inst Technol Goa, Dept Appl Sci, Ponda 403401, Goa, India
[2] Natl Inst Technol, Dept Phys, Calicut 673601, Kerala, India
关键词:
lead free metal halide perovskite;
inorganic bismuth based perovskite;
caesium bismuth iodide perovskite;
single crystal;
Cs3Bi2I9 thin film;
optoelectronic applications;
crystal growth;
PHOTOVOLTAIC PERFORMANCE;
WATER;
A(3)M(2)I(9);
INTERFACE;
SPECTRA;
BISMUTH;
FILMS;
RB;
BI;
CS;
D O I:
10.1088/1361-6641/ad08dd
中图分类号:
TM [电工技术];
TN [电子技术、通信技术];
学科分类号:
0808 ;
0809 ;
摘要:
In recent years, caesium bismuth iodide (Cs3Bi2I9), a lead (Pb)-free halide perovskite, has drawn more attention as a potential material than traditional semiconductor materials due to its lack of Pb toxicity and its outstanding stability against atmospheric air and moisture. Herein, the inverse temperature crystallization method is adopted to grow high-quality hexagonal-phase Cs3Bi2I9 perovskite single crystals. Furthermore, a Cs3Bi2I9 perovskite thin film is fabricated by a solution process using the two-step spin coating technique. A collective analysis of the structural properties, surface morphology, thermal stability, phase transition, and optoelectronic properties of these single crystal and polycrystalline thin films provides a comprehensive understanding and design strategy to develop environmentally stable, Pb-free, and high-performance photovoltaic and optoelectronic devices based on Cs3Bi2I9 perovskite. The findings of this study contribute to the advancement of perovskite-based technologies and pave the way for their successful integration into the renewable energy and optoelectronics industries.
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Belarusian State Univ, AN Sevchenko Inst Appl Phys Problems, Minsk 220030, BELARUS Belarusian State Univ, AN Sevchenko Inst Appl Phys Problems, Minsk 220030, BELARUS

Umreiko, D. S.
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机构:
Belarusian State Univ, AN Sevchenko Inst Appl Phys Problems, Minsk 220030, BELARUS Belarusian State Univ, AN Sevchenko Inst Appl Phys Problems, Minsk 220030, BELARUS