Exploring the synthesis, structure, and optoelectronic properties of lead-free halide perovskite Cs3Bi2I9 in single crystal and polycrystalline forms

被引:3
作者
Sujith, P. [1 ]
Parne, Saidi Reddy [1 ]
Abhinav, T. [2 ]
机构
[1] Natl Inst Technol Goa, Dept Appl Sci, Ponda 403401, Goa, India
[2] Natl Inst Technol, Dept Phys, Calicut 673601, Kerala, India
关键词
lead free metal halide perovskite; inorganic bismuth based perovskite; caesium bismuth iodide perovskite; single crystal; Cs3Bi2I9 thin film; optoelectronic applications; crystal growth; PHOTOVOLTAIC PERFORMANCE; WATER; A(3)M(2)I(9); INTERFACE; SPECTRA; BISMUTH; FILMS; RB; BI; CS;
D O I
10.1088/1361-6641/ad08dd
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
In recent years, caesium bismuth iodide (Cs3Bi2I9), a lead (Pb)-free halide perovskite, has drawn more attention as a potential material than traditional semiconductor materials due to its lack of Pb toxicity and its outstanding stability against atmospheric air and moisture. Herein, the inverse temperature crystallization method is adopted to grow high-quality hexagonal-phase Cs3Bi2I9 perovskite single crystals. Furthermore, a Cs3Bi2I9 perovskite thin film is fabricated by a solution process using the two-step spin coating technique. A collective analysis of the structural properties, surface morphology, thermal stability, phase transition, and optoelectronic properties of these single crystal and polycrystalline thin films provides a comprehensive understanding and design strategy to develop environmentally stable, Pb-free, and high-performance photovoltaic and optoelectronic devices based on Cs3Bi2I9 perovskite. The findings of this study contribute to the advancement of perovskite-based technologies and pave the way for their successful integration into the renewable energy and optoelectronics industries.
引用
收藏
页数:15
相关论文
共 81 条
[51]   Structure of water at the electrified platinum-water interface:: A study by surface-enhanced infrared absorption spectroscopy [J].
Osawa, Masatoshi ;
Tsushima, Minoru ;
Mogami, Hirokazu ;
Samjeske, Gabor ;
Yamakata, Akira .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (11) :4248-4256
[52]   Properties of isolated single crystalline and textured polycrystalline nano/sub-micrometre Nd2Fe14B particles obtained from milling of HDDR powder [J].
Pal, S. K. ;
Gueth, K. ;
Woodcock, T. G. ;
Schultz, L. ;
Gutfleisch, O. .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2013, 46 (37)
[53]   Bismuth Based Hybrid Perovskites A3Bi2I9 (A: Methylammonium or Cesium) for Solar Cell Application [J].
Park, Byung-Wook ;
Philippe, Bertrand ;
Zhang, Xiaoliang ;
Rensmo, Hakan ;
Boschloo, Gerrit ;
Johansson, Erik M. J. .
ADVANCED MATERIALS, 2015, 27 (43) :6806-+
[54]   Bismuth Iodide Perovskite Materials for Solar Cell Applications: Electronic Structure, Optical Transitions, and Directional Charge Transport [J].
Pazoki, Meysam ;
Johansson, Malin B. ;
Zhu, Huimin ;
Broqvist, Peter ;
Edvinsson, Tomas ;
Boschloo, Gerrit ;
Johansson, Erik M. J. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2016, 120 (51) :29039-29046
[55]   Hybrid perovskite single crystal with extended absorption edge and environmental stability: Towards a simple and easy synthesis procedure [J].
Pratheek, M. ;
Predeep, P. .
MATERIALS CHEMISTRY AND PHYSICS, 2020, 239
[56]   Highly stable lead-free Cs3Bi2I9 perovskite nanoplates for photodetection applications [J].
Qi, Zhaoyang ;
Fu, Xianwei ;
Yang, Tiefeng ;
Li, Dong ;
Fan, Peng ;
Li, Honglai ;
Jiang, Feng ;
Li, Lihui ;
Luo, Ziyu ;
Zhuang, Xiujuan ;
Pan, Anlian .
NANO RESEARCH, 2019, 12 (08) :1894-1899
[57]   Charge carrier dynamics study and morphology optimization in solvent annealed CH3NH3PbI3 perovskite for air processed stable solar cell application [J].
Raghav, Anubhav ;
Singh, Shivam ;
Moghe, Dhanashree ;
Sharma, Shailendra ;
Kabra, Dinesh ;
Satapathi, Soumitra .
CHEMICAL PHYSICS, 2019, 526
[58]   Controllable intermediates by molecular self-assembly for optimizing the fabrication of large-grain perovskite films via one-step spin-coating [J].
Ren, Ying-Ke ;
Liu, Shi-Dong ;
Duan, Bin ;
Xu, Ya-Feng ;
Li, Zhao-Qian ;
Huang, Yang ;
Hu, Lin-Hua ;
Zhu, Jun ;
Dai, Song-Yuan .
JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 705 :205-210
[59]   Evaluation of structural, mechanical, and cellular behavior of electrospun poly-3-hydroxybutyrate scaffolds loaded with glucosamine sulfate to develop cartilage tissue engineering [J].
Shahali, Zahra ;
Karbasi, Saeed ;
Avadi, Mohammad Reza ;
Semnani, Dariush ;
Zargar, Elham Naghash ;
HashemiBeni, Batoul .
INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS AND POLYMERIC BIOMATERIALS, 2017, 66 (12) :589-602
[60]   MODELING OF STRUCTURES AND CALCULATION OF IR VIBRATIONAL SPECTRA OF N,N-DIMETHYLFORMAMIDE DIMERS BY DENSITY FUNCTIONAL THEORY [J].
Shundalau, M. B. ;
Chybirai, P. S. ;
Komyak, A. I. ;
Zazhogin, A. P. ;
Ksenofontov, M. A. ;
Umreiko, D. S. .
JOURNAL OF APPLIED SPECTROSCOPY, 2011, 78 (03) :326-336