A robust thorium-organic framework as a bifunctional platform for iodine adsorption and Cr(vi) sensitization

被引：8

作者：

Fu, Yiran ^{[1
,3
]}

Wang, Xue ^{[1
]}

Ju, Yu ^{[1
]}

Zheng, Zhaofa ^{[1
,3
]}

Jian, Jie ^{[2
]}

Li, Zi-Jian ^{[1
,3
]}

Jin, Chan ^{[1
,3
]}

Wang, Jian-Qiang ^{[1
,3
]}

Lin, Jian ^{[2
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Appl Phys, 2019 Jia Luo Rd, Shanghai 201800, Peoples R China

[2] Xi An Jiao Tong Univ, Sch Nucl Sci & Technol, Xian 710049, Peoples R China

[3] Univ Chinese Acad Sci, 19 A Yuquan Rd, Beijing 100049, Peoples R China

来源：

DALTON TRANSACTIONS | 2023年 / 52卷 / 05期

基金：

中国国家自然科学基金;

关键词：

HIGH-CAPACITY; PARADIGM; MOFS;

D O I：

10.1039/d2dt03623a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Simple synthetic modulation based on thorium nitrate and tris((4-carboxyl)phenylduryl)amine (H(3)TCBPA) gives rise to a new thorium-based metal-organic framework, Th-TCBPA, which features excellent hydrolytic and thermal stabilities. Incorporating electron-rich TCBPA(3-) linkers not only endows Th-TCBPA with high adsorption capacity toward radioiodine vapor, but also makes it a luminescence sensor for the highly sensitive and selective detection of Cr(vi) anions.

引用

页码：1177 / 1181

页数：5

共 41 条

[1] Autoluminescent Metal-Organic Frameworks (MOFs): Self-Photoemission of a Highly Stable Thorium MOF [J].

Andreo, Jacopo ;

Priola, Emanuele ;

Alberto, Gabriele ;

Benzi, Paola ;

Marabello, Domenica ;

Proserpio, Davide M. ;

Lamberti, Carlo ;

Diana, Eliano .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (43) :14144-14149

[2] New developments in the Inorganic Crystal Structure Database (ICSD): accessibility in support of materials research and design [J].

Belsky, A ;

Hellenbrandt, M ;

Karen, VL ;

Luksch, P .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 :364-369

[3] Chromate separation by selective crystallization [J].

Chen, Xijian ;

Dai, Xing ;

Xie, Rongzhen ;

Li, Jie ;

Khayambashi, Afshin ;

Xu, Lei ;

Yang, Chuang ;

Shen, Nannan ;

Wang, Yaxing ;

He, Linwei ;

Zhang, Yugang ;

Xiao, Chengliang ;

Chai, Zhifang ;

Wang, Shuao .

CHINESE CHEMICAL LETTERS, 2020, 31 (07) :1974-1977

[4] Actinide-based MOFs: a middle ground in solution and solid-state structural motifs [J].

Dolgopolova, Ekaterina A. ;

Rice, Allison M. ;

Shustova, Natalia B. .

CHEMICAL COMMUNICATIONS, 2018, 54 (50) :6472-6483

[5] Multifaceted Modularity: A Key for Stepwise Building of Hierarchical Complexity in Actinide Metal-Organic Frameworks [J].

Dolgopolova, Ekaterina A. ;

Ejegbaywo, Otega A. ;

Martin, Corey R. ;

Smith, Mark D. ;

Setyawan, Wahyu ;

Karakalos, Stavros G. ;

Henager, Charles H. ;

zur Loye, Hans-Conrad ;

Shustova, Natalia B. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (46) :16852-16861

[6] Thermodynamics and Electronic Properties of Heterometallic Multinuclear Actinide-Containing Metal-Organic Frameworks with "Structural Memory" [J].

Ejegbavwo, Otega A. ;

Martin, Corey R. ;

Olorunfemi, Oyindamola A. ;

Leith, Gabrielle A. ;

Ly, Richard T. ;

Rice, Allison M. ;

Dolgopolova, Ekaterina A. ;

Smith, Mark D. ;

Karakalos, Stavros G. ;

Birkner, Nancy ;

Powell, Brian A. ;

Pandey, Shubham ;

Koch, Robert J. ;

Misture, Scott T. ;

Loye, Hans-Conrad Zur ;

Phillpot, Simon R. ;

Brinkman, Kyle S. ;

Shustova, Natalia B. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (29) :11628-11640

[7] A Cationic Metal-Organic Solid Solution Based on Co(II) and Zn(II) for Chromate Trapping [J].

Fei, Honghan ;

Han, Cari S. ;

Robins, Jeremy C. ;

Oliver, Scott R. J. .

CHEMISTRY OF MATERIALS, 2013, 25 (05) :647-652

[8] Anion Exchange of the Cationic Layered Material [Pb2F2]2+ [J].

Fei, Honghan ;

Pham, Catherine H. ;

Oliver, Scott R. J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (26) :10729-10732

[9] A New Paradigm for Anion Trapping in High Capacity and Selectivity: Crystal-to-Crystal Transformation of Cationic Materials [J].

Fei, Honghan ;

Bresler, Marc R. ;

Oliver, Scott R. J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (29) :11110-11113

[10] Rational tuning of thorium-organic frameworks by reticular chemistry for boosting radionuclide sequestration [J].

Feng, Han ;

Xiong, Xiaohong ;

Gong, Lele ;

Zhang, Huiping ;

Xu, Ying ;

Feng, Xuefeng ;

Luo, Feng .

NANO RESEARCH, 2022, 15 (02) :1472-1478

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