Increasing maleic anhydride selectivity for n-butane oxidation by Y-modified VPO catalysts

被引：5

作者：

Li, Wenjiao ^{[1
,2
]}

Xiao, Yong ^{[1
]}

Guo, Shupeng ^{[1
]}

Jia, Litao ^{[1
,3
]}

Guo, Heqin ^{[1
]}

Li, Debao ^{[1
,3
]}

机构：

[1] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[3] Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China

来源：

FUEL | 2023年 / 333卷

关键词：

N-butane oxidation; Maleic anhydride; Y-modified VPO catalyst; PHOSPHORUS OXIDE CATALYST; DEEP-EUTECTIC SOLVENTS; IN-SITU RAMAN; ALDOL CONDENSATION; LIGHT ALKANES; ACETIC-ACID; PHOSPHATE; DEHYDROGENATION; PERFORMANCE; FORMALDEHYDE;

D O I：

10.1016/j.fuel.2022.126214

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

In the present study, a series of VPO catalysts with different amount of Y were prepared by organic phase method and activated in butane-air atmosphere. The catalytic performance was tested by the selective oxidation of n -butane to maleic anhydride (MA). The catalysts were characterized by SEM, TG, XRD, Raman, XPS, H2-TPR and NH3-TPD techniques. The characterization results showed that the addition of appropriate amount of Y can increase the amount and stability of the rose-like flower clusters of VPO precursors. Meanwhile, the addition of Y greatly increased the proportion of lattice oxygen on catalyst surface and changed the surface acidity of VPO catalyst. As a result, the selectivity and yield of MA were greatly improved by introducing the right amount of Y.

引用

页数：10

共 53 条

[1] Novel Synthesis Method of porous VPO catalysts with fibrous structure by Electrospinning [J].

Berenguer, R. ;

Fornells, J. ;

Garcia-Mateos, F. J. ;

Guerrero-Perez, M. O. ;

Rodriguez-Mirasol, J. ;

Cordero, T. .

CATALYSIS TODAY, 2016, 277 :266-273

[2] An investigation on surface reactivity of Nb-doped vanadyl pyrophosphate catalysts by reactivity experiments and in situ Raman spectroscopy [J].

Caldarelli, A. ;

Banares, M. A. ;

Cortelli, C. ;

Luciani, S. ;

Cavani, F. .

CATALYSIS SCIENCE & TECHNOLOGY, 2014, 4 (02) :419-427

[3] The design of a new ZrO2-supported V/P/O catalyst for n-butane oxidation to maleic anhydride The build-up of the active phase during thermal treatment [J].

Caldarelli, A. ;

Cavani, F. ;

Folco, F. ;

Luciani, S. ;

Cortelli, C. ;

Leanza, R. .

CATALYSIS TODAY, 2010, 157 (1-4) :204-210

[4] Surface Dynamics of A Vanadyl Pyrophosphate Catalyst for n-Butane Oxidation to Maleic Anhydride: An In Situ Raman and Reactivity Study of the Effect of the P/V Atomic Ratio [J].

Cavani, Fabrizio ;

Luciani, Silvia ;

Degli Esposti, Elisa ;

Cortelli, Carlotta ;

Leanza, Roberto .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (05) :1646-1655

[5] The Critical Role of Phosphate in Vanadium Phosphate Oxide for the Catalytic Activation and Functionalization of n-Butane to Maleic Anhydride [J].

Cheng, Mu-Jeng ;

Goddard, William A., III .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (12) :4600-4603

[6] The magnetic and electronic structure of vanadyl pyrophosphate from density functional theory [J].

Cheng, Mu-Jeng ;

Nielsen, Robert J. ;

Tahir-Kheli, Jamil ;

Goddard, William A., III .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (20) :9831-9838

[7]

Dai F, 2020, CATAL LETT, V151, P255

[8] Synthesis of vanadium phosphorus oxide catalysts promoted by iron-based ionic liquids and their catalytic performance in selective oxidation of n-butane [J].

Dai, Fei ;

Li, Zihang ;

Chen, Xuejing ;

He, Bin ;

Liu, Ruixia ;

Zhang, Suojiang .

CATALYSIS SCIENCE & TECHNOLOGY, 2018, 8 (17) :4515-4525

[9] Vanadium phosphorus oxide catalyst modified by niobium doping for mild oxidation of n-butane to maleic anhydride [J].

de Farias, AMD ;

Gonzalez, WD ;

de Oliveira, PGP ;

Eon, JG ;

Herrmann, JM ;

Aouine, M ;

Loridant, S ;

Volta, JC .

JOURNAL OF CATALYSIS, 2002, 208 (01) :238-246

[10] Control of the crystal morphology of VOHPO4•0.5H2O precursors prepared via light alcohols-assisted solvothermal synthesis and influence on the selective oxidation of n-butane [J].

Dinh, M. T. Nguyen ;

Nguyen, T. L. ;

Phan, M. D. ;

Dinh, L. Nguyen ;

Truong, Q. D. ;

Bordes-Richard, E. .

JOURNAL OF CATALYSIS, 2019, 377 :638-651

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