Crystal structure and solid-state luminescence properties of [Tb(H2O)9]Cl(C10H6O4S4)2 (C10H6O4S42-=2,6-naphthalenedisulfonate)

被引：7
|
作者：
Liu, Ming-Qing [2 ]
Chen, Wen-Tong [1 ,2 ,3 ]
Wei, Lijun [1 ]
Zhong, Qiu-Yue [1 ]
Yin, Chuan-Kang [1 ]
Yi, Xiu-Guang [1 ]
机构：
[1] Jinggangshan Univ, Hum Acid Utilizat Engn Res Ctr Jiangxi Prov, Sch Chem & Chem Engn,Jiangxi Prov Key Lab Coordin, Inst Appl Chem,Jian Key Lab Photoelect Crystal Ma, Jian 343009, Jiangxi, Peoples R China
[2] Jishui Jincheng Technol Co Ltd, Jian 343009, Jiangxi, Peoples R China
[3] Wuyi Univ, Dept Ecol & Resources Engn, Fujian Key Lab Ecoind Green Technol, Wuyishan 354300, Fujian, Peoples R China
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2023年 / 53卷 / 02期
关键词：
crystal; terbium; lanthanide; photoluminescence; band gap; AQUEOUS-PHASE DETECTION; TB-ORGANIC-FRAMEWORKS; IONIC LIQUID; COMPLEXES; POLYMERS; PHOTOLUMINESCENCE;
D O I：
10.1007/s10870-022-00963-z
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A terbium 2,6-naphthalenedisulfonic acid compound, [Tb(H2O)(9)]Cl(C10H6O4S4)(2) (C10H6O4S42- = 2,6-naphthalenedisulfonate), is prepared and characterized by single-crystal X-ray diffraction. This compound is characterized by an isolated structure with the terbium ion possessing a mono-capped square antiprism coordination geometry. The [Tb(H2O)(9)](3+) cations and (2,6-naphthalenedisulfonic acid)(2-) anions are linked by hydrogen-bonding interactions to yield a three-dimensional supramolecular network. The solid state luminescence spectrum reveals that this compound shows the strongest emission band in the red region. The luminescence emission peaks can be ascribed to the characteristic emissions of the 4f electron intrashell transitions D-5(4) -> F-7(5), D-5(4) -> F-7(4) and D-5(4) -> F-7(2) of the Tb3+ ion. The CIE (Commission Internationale de L'Eclairage) chromaticity coordinates are (0.5647, 0.4338). Solid-state UV/Vis diffuse reflectance spectra reveal that compound 1 shows a wide optical band gap of 4.92 eV. [GRAPHICS] .
引用
收藏
页码：266 / 272
页数：7
相关论文
共 50 条
  • [11] Crystal structure of tetra-aqua-bis-(pyridine-4-carboxamide-N)-nickel(II) 1,5-naphthalenedisulfonate-isonicotinamide-water (1:2:4), [Ni(H2O)4(C6H6N2O)2][C10H6S2O6]•2C6H6N2O•4H2O, C34H46N8NiO18S2
    Lian, Zhaoxun
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2012, 227 (04): : 479 - 480
  • [12] Crystal structure and bioactivity of complex [Gd(C10H9N2O4)(C10H8N2O4)(H2O)3]2•phen•4H2O
    He, SY
    Yang, R
    Wu, WT
    Shi, QZ
    Wang, DQ
    An, DR
    CHINESE JOURNAL OF CHEMISTRY, 2005, 23 (09) : 1198 - 1202
  • [13] Synthesis, crystal structure and properties of the binuclear complex [Sm2(C10H9N2O4)2(C10H8N2O4)2(H2O)4]
    Liu, Feng
    Zhang, Weiping
    He, Shuiyang
    Wang, Liujie
    Liu, Xiangrong
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2008, 38 (10) : 755 - 760
  • [14] Synthesis, Crystal Structure and Properties of the Binuclear Complex [Sm2(C10H9N2O4)2(C10H8N2O4)2(H2O)4]
    Feng Liu
    Weiping Zhang
    Shuiyang He
    Liujie Wang
    Xiangrong Liu
    Journal of Chemical Crystallography, 2008, 38 : 755 - 760
  • [15] Crystal structure of triaquatriimidazolenickel(II) naphthalene-2,6-disulfonate monohydrate, [Co(C3H4N2)3(H2O)3][C10H6S2O6] • H2O
    Zhang, Yonghua
    Liu, Ping
    Feng, Zhiling
    Sun, Xiaojing
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2011, 226 (04): : 513 - 514
  • [16] Crystal structure of triaquatriimidazolecobalt(II) naphthalene-2,6-disulfonate monohydrate, [Co(C3H4N2)3(H2O)3][C10H6S2O6] • H2O
    Liu, Ping
    Liu, Zhen
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2008, 223 (04): : 498 - 500
  • [17] CRYSTAL STRUCTURE OF [Tm4（p-NO2C6H4CO2）12（H2O）10·2H2O
    Ma Jian-Fang Jin Zhong-Sheng Ni Jia-Zuan Changchun Institute of Applied Chemistry
    结构化学, 1991, (01) : 56 - 59
  • [18] Synthesis and crystal structure of [Ni(H2O)6]Cl2 (C6H12N4)2 · 4H2O
    Kokunov, Yu.V.
    Khmelevskaya, L.V.
    Gorbunova, Yu.E.
    Mikhajlov, Yu.N.
    1600, MAIK Nauka (47):
  • [19] Synthesis and crystal structure of [Ni(H2O)6]Cl2(C6H12N4)2 • 4H2O
    Kokunov, YV
    Khmelevskaya, LV
    Gorbunova, YE
    Mikhailov, YN
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2002, 47 (10) : 1463 - 1466
  • [20] Crystal structure of tri-aqua-(pyridine-4-carboxamide-N) copper(II) 2,7-naphthalenedisulfonate trihydrate, [Cu(H2O)3(C6H6N2O)2](C10H6O6S2)•3H2O, C22H30CuN4O14S2
    Li, Chunying
    Zhao, Ning
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2012, 227 (04): : 553 - 555
12345