Metallocene-Filled Single-Walled Carbon Nanotube Hybrids

被引：5
|
作者：
Kharlamova, Marianna V. V. [1 ]
Kramberger, Christian [2 ]
机构：
[1] Slovak Acad Sci, Ctr Adv Mat Applicat CEMEA, Dubravska cesta 5807-9, Bratislava 84511, Slovakia
[2] Univ Vienna, Fac Phys, Boltzmanngasse 5, A-1090 Vienna, Austria
来源：
NANOMATERIALS | 2023年 / 13卷 / 04期
关键词：
metallocene; carbon nanotube; electronic properties; Raman spectroscopy; near edge X-ray absorption fine structure spectroscopy; photoemission spectroscopy; optical absorption spectroscopy; INNER TUBE GROWTH; CHIRALITY-DEPENDENT GROWTH; CHEMICAL-VAPOR-DEPOSITION; IN-SITU OBSERVATION; GAS-PHASE SYNTHESIS; ELECTRONIC-STRUCTURE; CHARGE-TRANSFER; FULLERENE ENCAPSULATION; RAMAN-SCATTERING; MAGNETIC-PROPERTIES;
D O I：
10.3390/nano13040774
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this paper, the growth mechanism, structure, growth processes, growth kinetics, and optical, vibronic and electronic properties of metallocene-filled single-walled carbon nanotubes (SWCNTs) are considered. A description of the procedures used to fill the nanotubes is provided. An investigation of doping effects on metallicity-mixed SWCNTs filled with metallocenes by Raman spectroscopy, near edge X-ray absorption fine structure spectroscopy, photoemission spectroscopy, and optical absorption spectroscopy is described. The studies of doping effects on metallicity-sorted SWCNTs filled with metallocenes are discussed. Doping effects in metallicity-mixed and sorted SWCNTs upon the chemical transformation of encapsulated molecules are analyzed. A discussion of the modification of the electronic properties of filled SWCNTs is presented. Applications of metallocene-filled SWCNTs in electrochemistry, thermoelectric power generation, chemical sensors, and magnetic recording are discussed.
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页数：36
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