MoS2-Mediated Epitaxial Plating of Zn Metal Anodes

被引：37

作者：

Wang, Yizhou ^{[1
]}

Xu, Xiangming ^{[1
]}

Yin, Jian ^{[1
]}

Huang, Gang ^{[1
]}

Guo, Tianchao ^{[1
]}

Tian, Zhengnan ^{[1
]}

Alsaadi, Rajeh ^{[1
]}

Zhu, Yunpei ^{[1
]}

Alshareef, Husam N. ^{[1
]}

机构：

[1] King Abdullah Univ Sci & Technol KAUST, Phys Sci & Engn PSE Div, Mat Sci & Engn, Thuwal 239556900, Saudi Arabia

来源：

ADVANCED MATERIALS | 2023年 / 35卷 / 06期

关键词：

crystal orientation; epitaxial growth; molybdenum disulfide; zinc dendrite; zinc metal anode; ELECTRODEPOSITION; PERSPECTIVES; FUNDAMENTALS; LITHIUM;

D O I：

10.1002/adma.202208171

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-based anodes (Li, Zn, etc.) are regarded as promising solutions for next-generation advanced batteries due to their high theoretical specific capacities. However, most of these metal anodes suffer from dendrite growth, which severely restricts their practical applications. Recently, epitaxial anode metal deposition by choosing a suitable substrate has received tremendous attention as an effective strategy to suppress dendrites. However, the epitaxial relationship between plated metal and the substrate has been a subject of debate. Herein, large-area, mono-orientated 2D material (MoS2) is used, for the first time, to electrodeposit truly epitaxial Zn anodes. The continuous (without edges) mono-orientated MoS2 films are shown to be an effective strategy for suppressing metal dendrites. In addition, the epitaxial nature of the electrodeposited Zn anode is proven by pole figure analysis, which provides the first demonstration of truly epitaxial Zn anode growth over large area as metal anode protection strategy through epitaxy.

引用

页数：8

共 36 条

[1] In Situ Detection of Active Edge Sites in Single-Layer MoS2 Catalysts [J].

Bruix, Albert ;

Fuchtbauer, Henrik Gobel ;

Tuxen, Anders K. ;

Walton, Alexander S. ;

Andersen, Mie ;

Porsgaard, Soren ;

Besenbacher, Flemming ;

Hammer, Bjork ;

Lauritsen, Jeppe V. .

ACS NANO, 2015, 9 (09) :9322-9330

[2] Fluorinated solid electrolyte interphase enables highly reversible solid-state Li metal battery [J].

Fan, Xiulin ;

Ji, Xiao ;

Han, Fudong ;

Yue, Jie ;

Chen, Ji ;

Chen, Long ;

Deng, Tao ;

Jiang, Jianjun ;

Wang, Chunsheng .

SCIENCE ADVANCES, 2018, 4 (12)

[3] Induction of Planar Sodium Growth on MXene (Ti3C2Tx)-Modified Carbon Cloth Hosts for Flexible Sodium Metal Anodes [J].

Fang, Yongzheng ;

Lian, Ruqian ;

Li, Huipeng ;

Zhang, Ying ;

Gong, Zhe ;

Zhu, Kai ;

Ye, Ke ;

Yan, Jun ;

Wang, Guiling ;

Gao, Yu ;

Wei, Yingjin ;

Cao, Dianxue .

ACS NANO, 2020, 14 (07) :8744-8753

[4] Fundamentals and perspectives of electrolyte additives for aqueous zinc-ion batteries [J].

Guo, Shan ;

Qin, Liping ;

Zhang, Tengsheng ;

Zhou, Miao ;

Zhou, Jiang ;

Fang, Guozhao ;

Liang, Shuquan .

ENERGY STORAGE MATERIALS, 2021, 34 :545-562

[5] Self-gating in semiconductor electrocatalysis [J].

He, Yongmin ;

He, Qiyuan ;

Wang, Luqing ;

Zhu, Chao ;

Golani, Prafful ;

Handoko, Albertus D. ;

Yu, Xuechao ;

Gao, Caitian ;

Ding, Mengning ;

Wang, Xuewen ;

Liu, Fucai ;

Zeng, Qingsheng ;

Yu, Peng ;

Guo, Shasha ;

Yakobson, Boris I. ;

Wang, Liang ;

Seh, Zhi Wei ;

Zhang, Zhuhua ;

Wu, Minghong ;

Wang, Qi Jie ;

Zhang, Hua ;

Liu, Zheng .

NATURE MATERIALS, 2019, 18 (10) :1098-+

[6]

Kelso MV, 2019, SCIENCE, V364, P166, DOI [10.11896/j.issn.1005-023x.2019.12.h01, 10.1126/science.aaw6184]

[7] Reduced-Graphene-Oxide-Guided Directional Growth of Planar Lithium Layers [J].

Li, Nan ;

Zhang, Kun ;

Xie, Keyu ;

Wei, Wenfei ;

Gao, Yong ;

Bai, Maohui ;

Gao, Yuliang ;

Hou, Qian ;

Shen, Chao ;

Xia, Zhenhai ;

Wei, Bingqing .

ADVANCED MATERIALS, 2020, 32 (07)

[8] Developing High-Performance Lithium Metal Anode in Liquid Electrolytes: Challenges and Progress [J].

Li, Sa ;

Jiang, Mengwen ;

Xie, Yong ;

Xu, Hui ;

Jia, Junyao ;

Li, Ju .

ADVANCED MATERIALS, 2018, 30 (17)

[9] Electrolyte Strategies toward Better Zinc-Ion Batteries [J].

Liu, Cunxin ;

Xie, Xuesong ;

Lu, Bingan ;

Zhou, Jiang ;

Liang, Shuquan .

ACS ENERGY LETTERS, 2021, 6 (03) :1015-1033

[10] Tutorial review on structure - dendrite growth relations in metal battery anode supports [J].

Liu, Wei ;

Liu, Pengcheng ;

Mitlin, David .

CHEMICAL SOCIETY REVIEWS, 2020, 49 (20) :7284-7300

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