Synthesis and Porous Crystal Structure of a New Tetranuclear {Mn2IIMn2III} Cluster Based on a Calix[4]Arene Functionalized at the Upper Rim by Distal p-(4-Nitrophenyl)Diazenyl and p-tert-Butyl Groups

被引：0

作者：

Ovsyannikov, A. S. ^{[1
]}

Strelnikova, Yu. V. ^{[1
,2
]}

Iova, A. A. ^{[1
]}

Agarkov, A. S. ^{[1
,2
]}

Islamov, D. R. ^{[3
]}

Dorovatovskii, P. V. ^{[4
]}

Solovieva, S. E. ^{[1
]}

Antipin, I. S. ^{[1
]}

机构：

[1] Kazan Fed Univ, Kazan, Russia

[2] Russian Acad Sci, Kazan Sci Ctr, Arbuzov Inst Organ & Phys Chem, Kazan, Russia

[3] Russian Acad Sci, Kazan Sci Ctr, Lab Struct Anal Biomacromol, Kazan, Russia

[4] Natl Res Ctr Kurchatov Inst, Moscow, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2024年 / 65卷 / 02期

基金：

俄罗斯科学基金会;

关键词：

calix[4]arene; crystal structure; supramolecular chemistry; Mn(II); Mn(III); single-crystal XRD; azo derivatives; clusters; non-covalent interactions; CALIXARENES; ADDUCT; FAMILY;

D O I：

10.1134/S0022476624020094

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New crystalline {(Mn2Mn2III)-Mn-II} tetranuclear cluster is prepared by the interaction of manganese(II) chloride with calix[4]arene <bold>3</bold> functionalized at the upper rim by distal p-(4-nitrophenyl)diazenyl and p-tert-butyl groups displaying different electronic effects and sizes. The structure of the cluster is studied by single-crystal XRD. Due to the presence of (4-nitrophenyl)diazenyl moieties at the upper rim of the macrocyclic ligand, the molecules of the tetranuclear {(Mn2Mn2III)-Mn-II} clusters are involved in pi-stacking interactions leading to the formation of 2D supramolecular layers affording a porous crystal packing.

引用

页码：313 / 322

页数：10

共 12 条

[1] Synthesis and Porous Crystal Structure of a New Tetranuclear \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$\text{\{Mn}_2^{\text{II}}\text{Mn}_2^{\text{III}}\}$$\end{document} Cluster Based on a Calix[4]Arene Functionalized at the Upper Rim by Distal p-(4-Nitrophenyl)Diazenyl and p-tert-Butyl Groups
A. S. Ovsyannikov
Yu. V. Strelnikova
A. A. Iova
A. S. Agarkov
D. R. Islamov
P. V. Dorovatovskii
S. E. Solovieva
I. S. Antipin
Journal of Structural Chemistry, 2024, 65 (2) : 313 - 322
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[4] Effect of Adamantyl Groups Along the Upper Rim of the Macrocycle Backbone on the Crystal Structure of Mixed-Valence Mn2II Mn2III Manganese Complexes Based on Calix[4]Arene and 2,2'-Bipyrimidine
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[5] Controlled synthesis of mono-p-[(2,3-epoxy)propyl]- and mono-p-(2-oxoethyl)-tris-p-tert-butylcalix[4]arenes crystal structure determination of an epoxy calix[4]arene
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[6] Molecular design of calixarene part 4 -: Synthesis of novel double-armed p-(tert-butyl)calix[4]arene-derived amides and their lead(II)(Pb2+)-selective-electrode properties
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[7] SYNTHESIS AND REDUCTIVE COMPLEXATION PROPERTIES OF A CONE-CONFIGURATED TETRA[P-(TERT-BUTYL)]CALIX[4]ARENE INCORPORATING BIPYRIDYL AND PYRIDINE SUBUNITS - NMR CHARACTERIZATION AND CRYSTAL-STRUCTURE OF ITS CHIRAL COPPER(I) COMPLEX
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[8] Research on the synthesis of new silver cluster complexes by the insertion reaction of CS2 into Ag-S bonds (IV). Formation and crystal structure of a tetranuclear silver cluster complex (Ph3P)4Ag4Br4
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[9] Crystal structure of tetrachloro-5,11,17,23-tetra-tert-butyl-{[cis-(P,P)-25,26-bis(diphenylphosphinomethoxy)]-(P,P)-27,28-bis(diphenylphosphino- methoxy)calix[4]arene}platinum(II)digold(I) hexachloroform hemihydrate, C96H100Cl4O4P4AU2Pt • 6CHCl3-1/2H2O, an evidence for a weak CH-platinum interaction
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[10] Effect of Adamantyl Groups Along the Upper Rim of the Macrocycle Backbone on the Crystal Structure of Mixed-Valence \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$\text{\{Mn}_{\text{2}}^{\text{II}}\text{Mn}_{\text{2}}^{\text{III}}\text{\}}$$\end{document} Manganese Complexes Based on Calix[4]Arene and 2,2'-Bipyrimidine
I. V. Strelnikova
A. S. Ovsyannikov
A. A. Iova
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