Vivianite for Phosphorus Recovery from Digester Supernatant in Wastewater Treatment Plants

被引:1
作者
Amjad, Salman [1 ]
Christensen, Morten Lykkegaard [2 ]
Reitzel, Kasper [3 ]
Qu, Haiyan [1 ]
机构
[1] Univ Southern Denmark, Dept Green Technol, Campusvej 55, DK-5230 Odense M, Denmark
[2] Aalborg Univ, Dept Chem & Biosci, Fredrik Bajers Vej 7H, DK-9220 Aalborg, Denmark
[3] Univ Southern Denmark, Dept Biol, Campusvej 55, DK-5230 Odense M, Denmark
关键词
Digester supernatant; Metastable zone width; Phosphorus recovery; Vivianite crystallization; CALCIUM PHOSPHATES; CRYSTALLIZATION; SOLUBILITY;
D O I
10.1002/ceat.202300071
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Phosphorus (P) recovery by crystallization of vivianite in digester supernatant (DS) was investigated. A high recovery yield (> 90 %) was obtained with vivianite even for DS with low P concentration (74 mg L-1), as opposed to the formation of struvite and hydroxyapatite where the yield was lower than 50-60 %. Various strategies were tested to produce vivianite with large sizes and narrow size distribution, such as a controlled reagent dosing profile, self-seeded crystallization, and multistage cascade-seeded crystallization. The obtained results demonstrated that the main challenge in the development of vivianite P recovery is to promote crystal growth and to suppress secondary nucleation of vivianite during the crystallization process.
引用
收藏
页码:2321 / 2329
页数:9
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