Fabrication of Glass-Ceramic 3D Micro-Optics by Combining Laser Lithography and Calcination

被引：28

作者：

Balcas, Giedrius ^{[1
]}

Malinauskas, Mangirdas ^{[1
]}

Farsari, Maria ^{[2
]}

Juodkazis, Saulius ^{[3
,4
]}

机构：

[1] Vilnius Univ, Phys Fac, Laser Res Ctr, Sauletekio Ave 10, LT-10223 Vilnius, Lithuania

[2] IESL FORTH, N Plastira 100, Iraklion 70013, Greece

[3] Swinburne Univ Technol, Sch Sci, Opt Sci Ctr, Hawthorn, Vic 3122, Australia

[4] Tokyo Inst Technol, WRH Program Int Res Frontiers Initiat IRFI, Nagatsutacho,Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

ADVANCED FUNCTIONAL MATERIALS | 2023年 / 33卷 / 39期

关键词：

3D printing; additive manufacturing; advanced materials; calcination; laser direct writing; micro-optics; post-processing; INDUCED DAMAGE THRESHOLD; 2-PHOTON POLYMERIZATION; FEMTOSECOND LASER; REFRACTIVE-INDEX; DESIGN; MICROSTRUCTURES; PHOTORESISTS; DEPOSITION; LENS; NANOFABRICATION;

D O I：

10.1002/adfm.202215230

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This perspective is an overview of a recent direction in optical 3D printing, where polymerization of crosslinkable materials and nanomaterial fillers can be guided to the final structures and new composites via high temperature annealing (HTA). Defining 3D nano/micro-structures by ultrafast laser direct writing and tailoring their precursor composition with subsequent tunability of the final properties during 750-1500 degrees C HTA step takes place at the large surface-to-volume ratio conditions favoring efficient pyrolysis and calcination, which are required for exchange of chemical materials/gases between glass/ceramic phase and surrounding. Previously, unexplored inorganic material formation conditions in terms of fast thermal quenching, composition mixing and surface tension guided formation can be harnessed by glass making for creation of new materials endowed with preferable technical properties. An immediate application perspective for a high durability, integrated, and active 3D micro-optics is foreseen.

引用

页数：16

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