Investigation of Zn alloy coating with submicron phases on magnesium alloy by the novel hot-dip process

被引:1
作者
Hu, Chenglu [1 ]
Zhou, Xiong [1 ]
Zhang, Xinyue [1 ]
Zou, Qi [1 ]
Li, Dandan [1 ]
Ren, Liang [1 ]
Jiang, Yanchao [1 ]
Wang, Tong [1 ]
Le, Qichi [1 ]
机构
[1] Northeastern Univ, Key Lab Electromagnet Proc Mat, Minist Educ, 3-11 Wenhua Rd, Shenyang 110819, Peoples R China
关键词
Corrosion; Intermetallic alloys and compounds; Microstructure; Hot-dip; Coating;
D O I
10.1016/j.matlet.2023.135190
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A Zn alloy coating with submicron phases was fabricated on magnesium alloys by a novel hot-dip process, exhibiting excellent corrosion resistance. The microstructure and phases of coatings were characterized and their correlation with the corrosion performance was investigated. The results indicated that the coating immersed in Zn-3Mg molten bath for 4 s primarily consisted of submicron dot-like Zn phases with well-ordered distribution, while the coating immersed in Zn-3Mg molten bath for 7 s mainly comprised rod-like compact MgZn2 phases with a scattered distribution of Zn phase. The presence of these fine phases of coatings effectively impeded ion permeation in corrosive environments, leading to a significant enhancement in corrosion resistance. Notably, the exceptional corrosion resistance of the coating immersed for 4 s can be attributed to the submicron Zn phase with a grain size of 0.51 mu m, resulting in a 62-fold increase in low-frequency impedance value compared to the AZ31 alloy, and a 22-fold decrease in corrosion rate compared to the AZ31 alloy.
引用
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页数:4
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共 10 条
[1]   The high corrosion-resistance of ultra-high purity Mg-Ge alloy and its discharge performance as anode for Mg-air battery [J].
Chen, Xingrui ;
Venezuela, Jeffrey ;
Dargusch, Matthew .
ELECTROCHIMICA ACTA, 2023, 448
[2]   Research on CO2 mineralization of high temperature oxide film on magnesium alloy surface [J].
Cheng, Chunlong ;
Chen, Zheng ;
Fan, Yu ;
Wang, Lin ;
Xu, Jie ;
Le, Qichi .
MATERIALS LETTERS, 2023, 347
[3]   Corrosion behavior and protective performance of robustness mineralized layer formed on AZ80-0.38Nd (wt%) alloy [J].
Cheng, Chunlong ;
Chen, Zheng ;
Fan, Yu ;
Yao, Ruidong ;
Le, Qichi .
CORROSION SCIENCE, 2023, 214
[4]   Corrosion and discharge properties of Ca/Ge micro-alloyed Mg anodes for primary aqueous Mg batteries [J].
Deng, Min ;
Wang, Linqian ;
Hoeche, Daniel ;
Lamaka, Sviatlana V. ;
Snihirova, Darya ;
Jiang, Pingli ;
Zheludkevich, Mikhail L. .
CORROSION SCIENCE, 2020, 177
[5]   Designing lightweight multicomponent magnesium alloys with exceptional strength and high stiffness [J].
Gu, Zuohong ;
Zhou, Yunxuan ;
Dong, Quan ;
He, Guangming ;
Cui, Jinghao ;
Tan, Jun ;
Chen, Xianhua ;
Jiang, Bin ;
Pan, Fusheng ;
Eckert, Juergen .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2022, 855
[6]   The effects of Ca and Mn on the microstructure, texture and mechanical properties of Mg-4 Zn alloy [J].
Liu, Chunquan ;
Chen, Xianhua ;
Chen, Jiao ;
Atrens, Andrej ;
Pan, Fusheng .
JOURNAL OF MAGNESIUM AND ALLOYS, 2021, 9 (03) :1084-1097
[7]   Study of the corrosion behavior and mechanism of a hot-dipping Zn-6Al-3Mg alloy coating in 3.5 wt% neutral NaCl solution [J].
Wang, Shengxing ;
Ma, Xiaohan ;
Bai, Jintao ;
Du, Tiantian ;
Ma, Ruina ;
Du, An ;
Zhao, Xue ;
Fan, Yongzhe ;
Li, Guolu .
SURFACE & COATINGS TECHNOLOGY, 2023, 464
[8]   Simple and scalable synthesis of super-repellent multilayer nanocomposite coating on Mg alloy with mechanochemical robustness, high-temperature endurance and electric protection [J].
Wang, Shuqi ;
Wang, Yaming ;
Chen, Junchen ;
Zou, Yongchun ;
Ouyang, Jiahu ;
Jia, Dechang ;
Zhou, Yu .
JOURNAL OF MAGNESIUM AND ALLOYS, 2022, 10 (09) :2446-2459
[9]   Integrated three-dimensional characterization of reactive phase formation and coarsening during isothermal annealing of metastable Zn-3Mg-4Al eutectic [J].
Wang, Yeqing ;
Chao, Paul ;
Moniri, Saman ;
Gao, Jianrong ;
Volkenandt, Tobias ;
De Andrade, Vincent ;
Shahani, Ashwin J. .
MATERIALS CHARACTERIZATION, 2020, 170
[10]   Effect of grain size and volume fraction of eutectic structure on mechanical properties and corrosion behavior of as-cast Zn-Mg binary alloys [J].
Ye, Lifeng ;
Huang, He ;
Sun, Chao ;
Zhuo, Xiaoru ;
Dong, Qiangsheng ;
Liu, Huan ;
Ju, Jia ;
Xue, Feng ;
Bai, Jing ;
Jiang, Jinghua .
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, 2022, 16 :1673-1685