Sulfonimidamide as Directing Group for Pd-mediated ortho-C-H Chlorination of Arenes

被引：2
作者：
Ravindra, S. [1 ]
Jesin, C. P. Irfana [1 ,2 ]
Hariprasad, R. [1 ]
Natarajan, K. [1 ]
Priya, V. R. Padma [1 ]
Nandi, Ganesh Chandra [1 ]
机构：
[1] Natl Inst Technol Tiruchirappalli, Dept Chem, Tiruchirappalli 620015, Tamilnadu, India
[2] Indian Inst Sci Bengaluru, Dept Inorgan & Phys Chem, Bengaluru 560012, India
来源：
CHEMISTRYSELECT | 2024年 / 9卷 / 03期
关键词：
Directing group; C-H activation; Sulfonimidamides; HALIDES; FUNCTIONALIZATION; HALOGENATION;
D O I：
10.1002/slct.202304253
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Herein, sulfonimidamide (SIA) has been used as directing group for ortho-chlorination of arene of N-aroyl part of SIA. The Pd-mediated protocol uses N-chlorosuccinimide (NCS) as oxidant/chlorine source, and acetic acid as solvent. The products are obtained in moderate to good yields.
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页数：4
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