Synthesis and Characterization of ZnO Doped TiO2 Nanocomposites for Their Potential Photocatalytic and Antimicrobial Applications

被引:15
|
作者
Gunasekaran, Anguraj [1 ]
Rajamani, Ashok Kumar [1 ]
Masilamani, Chandrasekar [2 ]
Chinnappan, Inmozhi [3 ]
Ramamoorthy, Uthrakumar [4 ]
Kaviyarasu, Kasinathan [5 ,6 ]
机构
[1] Thiruvalluvar Govt Arts Coll, Dept Phys, Rasipuram 637401, Tamil Nadu, India
[2] Thiru A Govindasamy Govt Arts Coll, Dept Phys, Tindivanam 604307, Tamil Nadu, India
[3] Govt Arts Coll Women, Dept Phys, Salem 636008, Tamil Nadu, India
[4] Govt Arts Coll Autonomous, Dept Phys, Salem 636007, Tamil Nadu, India
[5] Univ South Africa UNISA, Coll Grad Studies, UNESCO UNISA Africo Chair Nanosci Nanotechnol Labs, POB 392, Pretoria, Gauteng Provinc, South Africa
[6] Natl Res Fdn NRF, Nanosci African Network NANOAFNET, iThemba LABS, Mat Res Grp MRG, 1 Old Faure Rd,7129 Somerset West,POB 722, ZA-7129 Pretoria, Western Cape Pr, South Africa
关键词
ZnO-doped TiO2; sol-gel method; antibiotic-resistant; phase analysis; pseudo-first-order kinetics; infected water contaminated; wastewater treatment; photocatalytic degradation; ZINC-OXIDE NANOPARTICLES; OPTICAL-PROPERTIES; THIN-FILMS; BROOKITE; ANATASE; PHOTOLUMINESCENCE; DEGRADATION; RUTILE; ANTIBACTERIAL; SOL;
D O I
10.3390/catal13020215
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
As a result of the sol-gel method, we were able to produce pure ZnO and ZnO-doped TiO2 nanocomposites. The hexagonal wurtzite phase in ZnO products was discovered by powder X-ray diffraction (XRD). ZnO products are typically hexagonal wurtzite crystallites, formed according to the Debye Scherrer formula. Nanocomposites with significant morphological changes were created using the sol-gel process, including those that resembled rocks. To determine the composition of Zn, O, and Ti atoms in the samples, a multidimensional X-ray analysis was performed. There is an energy gap between 3.61 eV, as determined by UV-vis spectroscopy. In this study, pure ZnO and ZnO-doped TiO2 nanocomposites were used to study the degradation of methylene blue (MB) under visible light irradiation. Over an irradiation course of 6 h, a ZnO-doped TiO2 composite (84%) were studied. As determined by the kinetic analysis, nanocomposites made from pure ZnO and ZnO-doped TiO2 followed pseudo-first-order kinetics. In the presence of ZnO-doped TiO2 nanocomposites, antibacterial activity was significantly improved. This was shown to be effective against Gram-positive and Gram-negative bacteria (Escherichia coli and B. sublittus). There is evidence that the metal oxide nanocomposites that are produced can be used as an appropriate antimicrobial and disinfection alternative, particularly in biomedical settings, as reported in more detail.
引用
收藏
页数:16
相关论文
共 50 条
  • [31] Synthesis and Characterization of CNT/TiO2/ZnO Composites with High Photocatalytic Performance
    Huang, Yanzhen
    Li, Rongkai
    Chen, Dongping
    Hu, Xinling
    Chen, Pengxin
    Chen, Zhibin
    Li, Dongxu
    CATALYSTS, 2018, 8 (04):
  • [32] Synthesis, characterization and photocatalytic applications of Zn-doped TiO2 nanoparticles by sol–gel method
    Dinkar V. Aware
    Shridhar S. Jadhav
    Applied Nanoscience, 2016, 6 : 965 - 972
  • [33] Synthesis and characterization of MWCNT/TiO2/Au nanocomposite for photocatalytic and antimicrobial activity
    Karthika, Viswanathan
    Arumugam, Ayyakannu
    IET NANOBIOTECHNOLOGY, 2017, 11 (01) : 113 - 118
  • [34] Hydrothermal synthesis of nanostructured TiO2 particles and characterization of their photocatalytic antimicrobial activity
    Erdural, Beril K.
    Yurum, Alp
    Bakir, Ufuk
    Karakas, Gurkan
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2008, 8 (02) : 878 - 886
  • [35] Synthesis and Structural Evolution of ZnO/TiO2 Nanocomposites
    Shervani, Suboohi
    Khan, Wasi
    Chaman, M.
    Naqvi, A. H.
    SOLID STATE PHYSICS, PTS 1 AND 2, 2012, 1447 : 277 - 278
  • [36] Preparation and characterization of Rb-doped TiO2 powders for photocatalytic applications
    Lu Jia
    Li-Mei Yang
    Wei Wang
    Song-Tao Huang
    Zheng Xu
    Rare Metals, 2024, 43 : 555 - 561
  • [37] Preparation and characterization of Rb-doped TiO2 powders for photocatalytic applications
    Jia, Lu
    Yang, Li-Mei
    Wang, Wei
    Huang, Song-Tao
    Xu, Zheng
    RARE METALS, 2024, 43 (02) : 555 - 561
  • [38] Preparation and characterization of Rb-doped TiO2 powders for photocatalytic applications
    Lu Jia
    Li-Mei Yang
    Wei Wang
    Song-Tao Huang
    Zheng Xu
    Rare Metals, 2024, 43 (02) : 555 - 561
  • [39] Synthesis and Characterization of Pure TiO2 and TiO2-Doped Bi2O3 Nanocomposites for Electrochemical Applications
    Synthiya, S.
    Thilagavathi, T.
    Uthrakumar, R.
    Alam, Mir Waqas
    Kaviyarasu, K.
    LUMINESCENCE, 2025, 40 (04)
  • [40] Enhancing photocatalytic performance: Studying the synthesis and characterization of AgI-tuned TiO2/ZnO hybrid ternary nanocomposites
    Rehman, Ghani Ur
    Othman, Mohd Hafiz Dzarfan
    Wahab, Roswanira Abdul
    Ismail, A. F.
    Goh, P. S.
    Khan, Ilyas
    Irfan, Muhammad
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2024, 192