Synthesis and Characterization of ZnO Doped TiO2 Nanocomposites for Their Potential Photocatalytic and Antimicrobial Applications

被引:15
|
作者
Gunasekaran, Anguraj [1 ]
Rajamani, Ashok Kumar [1 ]
Masilamani, Chandrasekar [2 ]
Chinnappan, Inmozhi [3 ]
Ramamoorthy, Uthrakumar [4 ]
Kaviyarasu, Kasinathan [5 ,6 ]
机构
[1] Thiruvalluvar Govt Arts Coll, Dept Phys, Rasipuram 637401, Tamil Nadu, India
[2] Thiru A Govindasamy Govt Arts Coll, Dept Phys, Tindivanam 604307, Tamil Nadu, India
[3] Govt Arts Coll Women, Dept Phys, Salem 636008, Tamil Nadu, India
[4] Govt Arts Coll Autonomous, Dept Phys, Salem 636007, Tamil Nadu, India
[5] Univ South Africa UNISA, Coll Grad Studies, UNESCO UNISA Africo Chair Nanosci Nanotechnol Labs, POB 392, Pretoria, Gauteng Provinc, South Africa
[6] Natl Res Fdn NRF, Nanosci African Network NANOAFNET, iThemba LABS, Mat Res Grp MRG, 1 Old Faure Rd,7129 Somerset West,POB 722, ZA-7129 Pretoria, Western Cape Pr, South Africa
关键词
ZnO-doped TiO2; sol-gel method; antibiotic-resistant; phase analysis; pseudo-first-order kinetics; infected water contaminated; wastewater treatment; photocatalytic degradation; ZINC-OXIDE NANOPARTICLES; OPTICAL-PROPERTIES; THIN-FILMS; BROOKITE; ANATASE; PHOTOLUMINESCENCE; DEGRADATION; RUTILE; ANTIBACTERIAL; SOL;
D O I
10.3390/catal13020215
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
As a result of the sol-gel method, we were able to produce pure ZnO and ZnO-doped TiO2 nanocomposites. The hexagonal wurtzite phase in ZnO products was discovered by powder X-ray diffraction (XRD). ZnO products are typically hexagonal wurtzite crystallites, formed according to the Debye Scherrer formula. Nanocomposites with significant morphological changes were created using the sol-gel process, including those that resembled rocks. To determine the composition of Zn, O, and Ti atoms in the samples, a multidimensional X-ray analysis was performed. There is an energy gap between 3.61 eV, as determined by UV-vis spectroscopy. In this study, pure ZnO and ZnO-doped TiO2 nanocomposites were used to study the degradation of methylene blue (MB) under visible light irradiation. Over an irradiation course of 6 h, a ZnO-doped TiO2 composite (84%) were studied. As determined by the kinetic analysis, nanocomposites made from pure ZnO and ZnO-doped TiO2 followed pseudo-first-order kinetics. In the presence of ZnO-doped TiO2 nanocomposites, antibacterial activity was significantly improved. This was shown to be effective against Gram-positive and Gram-negative bacteria (Escherichia coli and B. sublittus). There is evidence that the metal oxide nanocomposites that are produced can be used as an appropriate antimicrobial and disinfection alternative, particularly in biomedical settings, as reported in more detail.
引用
收藏
页数:16
相关论文
共 50 条
  • [1] SYNTHESIS, CHARACTERIZATION, AND PHOTOCATALYTIC BEHAVIOUR OF NANOCRYSTALLINE ZnO, TiO2 AND ZnO/TiO2 NANOCOMPOSITES
    Rajendar, V.
    Raghu, Y.
    Rajitha, B.
    Chakra, C. S.
    Rao, K. V.
    Park, S. H.
    JOURNAL OF OVONIC RESEARCH, 2017, 13 (03): : 101 - 111
  • [2] Synthesis and characterization of Y3+-doped TiO2 nanocomposites for photocatalytic applications
    Narayan, Himanshu
    Alemu, Hailemichael
    Macheli, Lebohang
    Thakurdesai, Madhavi
    Rao, T. K. Gundu
    NANOTECHNOLOGY, 2009, 20 (25)
  • [3] Green synthesis and characterization of TiO2 and Ag-doped TiO2 nanoparticles for photocatalytic and antimicrobial applications
    Uthiravel, Vijayakumar
    Narayanamurthi, Kirusarani
    Raja, Vasanth
    Anandhabasker, Sivarajakrishnan
    Kuppusamy, Krishnasamy
    INORGANIC CHEMISTRY COMMUNICATIONS, 2024, 170
  • [4] Ultrasonic-assisted synthesis of doped TiO2 nanocomposites: Characterization and evaluation of photocatalytic and antimicrobial activity
    Magesan, P.
    Ganesan, P.
    Umapathy, M. J.
    OPTIK, 2016, 127 (13): : 5171 - 5180
  • [5] Preparation, Characterization, and Photocatalytic Activity of TiO2/ZnO Nanocomposites
    Wang, Liqin
    Fu, Xiujun
    Han, Yang
    Chang, E.
    Wu, Haitao
    Wang, Haiying
    Li, Kuiying
    Qi, Xiaowen
    JOURNAL OF NANOMATERIALS, 2013, 2013
  • [6] Synthesis, characterization and photocatalytic activity of TiO2/ZnO-supported phosphomolybdic acid nanocomposites
    Taghavi, Mahmoud
    Tabatabaee, Masoumeh
    Ehrampoush, Mohammad Hasan
    Ghaneian, Mohammad Taghi
    Afsharnia, Mojtaba
    Alami, Ali
    Mardaneh, Jalal
    JOURNAL OF MOLECULAR LIQUIDS, 2018, 249 : 546 - 553
  • [7] Synthesis and Characterization of TiO2 Doped ZnO Microtubes
    Li, Yan
    CHINESE JOURNAL OF CHEMICAL PHYSICS, 2010, 23 (03) : 358 - 362
  • [8] Synthesis, characterization and photocatalytic activity of PdO/TiO2 and Pd/TiO2 nanocomposites
    Hossein Khojasteh
    Masoud Salavati-Niasari
    Ali Abbasi
    Farshid Azizi
    Morteza Enhessari
    Journal of Materials Science: Materials in Electronics, 2016, 27 : 1261 - 1269
  • [9] Synthesis, characterization and photocatalytic activity of PdO/TiO2 and Pd/TiO2 nanocomposites
    Khojasteh, Hossein
    Salavati-Niasari, Masoud
    Abbasi, Ali
    Azizi, Farshid
    Enhessari, Morteza
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2016, 27 (02) : 1261 - 1269
  • [10] On the synthesis, characterization and photocatalytic applications of nanostructured TiO2
    P. R. Mishra
    O. N. Srivastava
    Bulletin of Materials Science, 2008, 31