Pre-buried Interface Strategy for Stable Inverted Perovskite Solar Cells Based on Ordered Nucleation Crystallization

被引:15
作者
Dai, Runying [1 ]
Meng, Xiangchuan [2 ]
Zhang, Jiaqi [1 ]
Cai, Zhixing [1 ]
Tan, Licheng [2 ]
Chen, Yiwang [1 ,2 ,3 ]
机构
[1] Jiangxi Normal Univ, Natl Engn Res Ctr Carbohydrate Synth, Key Lab Fluorine & Silicon Energy Mat & Chem, Minist Educ, 99 Ziyang Ave, Nanchang 330022, Peoples R China
[2] Nanchang Univ, Inst Polymers & Energy Chem IPEC, Jiangxi Prov Key Lab New Energy Chem, 999 Xuefu Ave, Nanchang 330031, Peoples R China
[3] Peking Univ, Yangtze Delta Inst Optoelect, Nantong 226010, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
buried interfacial defects; inverted perovskite solar cells; nickel oxide; nucleation and crystallization; stability; EFFICIENT; OXIDE; LAYER; PASSIVATION; STABILITY;
D O I
10.1002/adfm.202305013
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The buried interface has important effect on carrier extraction and nonradiative recombination of perovksite solar cells (PSCs). Herein, to inactivate the buried interfacial defects of perovskite and boost the crystallization quality of perovskite film, 3-amino-1-adamantanol (AAD) serves as a pre-buried interface modifier on nickel oxide (NiOx) surface to regulate the nucleation and crystallization process of perovskite precursor. The amino and hydroxyl groups in AAD molecule can synchronously coordinate with nickel ion (Ni3+) in NiOx and lead ion in perovskite, respectively. The dual action favors the ordered arrangement of AAD molecules between NiOx and perovskite, which not only enhances hole extraction in hole transport layer, but also provides active sites for homogeneous nucleation. Furthermore, AAD modifier blocks the unfavorable reaction between Ni3+ and perovskite, and effectively passivates the buried interfacial defects. The optimal inverted PSCs achieve a champion power conversion efficiency of 22.21% with negligible hysteresis, favorable thermal, optical, and long-term stability. Thus, this strategy of modulating perovskite nucleation and crystallization by pre-buried modifier is feasible for achieving efficient and stable inverted perovskite solar cells.
引用
收藏
页数:10
相关论文
共 50 条
  • [21] Improved interfacial adhesion for stable flexible inverted perovskite solar cells
    Dou, Jie
    Song, Qizhen
    Ma, Yue
    Wang, Hao
    Yuan, Guizhou
    Wei, Xueyuan
    Niu, Xiuxiu
    Ma, Sai
    Yang, Xiaoyan
    Dou, Jing
    Liu, Shaocheng
    Zhou, Huanping
    Zhu, Cheng
    Chen, Yihua
    Li, Yujing
    Bai, Yang
    Chen, Qi
    JOURNAL OF ENERGY CHEMISTRY, 2023, 76 : 288 - 294
  • [22] Suppressing Oxidation at Perovskite-NiOx Interface for Efficient and Stable Tin Perovskite Solar Cells
    Li, Bo
    Zhang, Chunlei
    Gao, Danpeng
    Sun, Xianglang
    Zhang, Shoufeng
    Li, Zhen
    Gong, Jianqiu
    Li, Shuai
    Zhu, Zonglong
    ADVANCED MATERIALS, 2024, 36 (17)
  • [23] Modification of a Buried Interface with Bulky Organic Cations for Highly Stable Flexible Perovskite Solar Cells
    Dasgupta, Shyantan
    Zuraw, Wiktor
    Ahmad, Taimoor
    Castriotta, Luigi Angelo
    Radicchi, Eros
    Mroz, Wojciech
    Scigaj, Mateusz
    Pawlaczyk, Lukasz
    Tamulewicz-Szwajkowska, Magdalena
    Trzcinski, Marek
    Serafinczuk, Jaroslaw
    Mosconi, Edoardo
    Di Carlo, Aldo
    De Angelis, Filippo
    Dudkowiak, Alina
    Wojciechowski, Konrad
    ACS APPLIED ENERGY MATERIALS, 2022, 5 (12) : 15114 - 15124
  • [24] Chemical anti-corrosion strategy for stable inverted perovskite solar cells
    Li, Xiaodong
    Fu, Sheng
    Zhang, Wenxiao
    Ke, Shanzhe
    Song, Weijie
    Fang, Junfeng
    SCIENCE ADVANCES, 2020, 6 (51)
  • [25] Buried Interface Passivation with 3,4,5-Trifluorophenylboronic Acid Enables Efficient and Stable Inverted Perovskite Solar Cells
    Yang, Jiansheng
    Zhao, Zhenhua
    Ding, Changzeng
    Zhang, Lianping
    Gao, Xiaomei
    Huang, Rong
    Li, Zhiyun
    Luo, Qun
    Fan, Bin
    Tian, Qingyong
    Yan, Lingpeng
    Guo, Kunpeng
    Yang, Yongzhen
    Ma, Chang-Qi
    ACS APPLIED MATERIALS & INTERFACES, 2025, 17 (11) : 16844 - 16854
  • [26] Buried interface bridging for inverted cesium-formamidinium triiodide perovskite solar cells with long operational stability
    Zhang, Chenhui
    Liang, Chunjun
    Sun, Fulin
    Zhu, Ting
    Huang, Xinghai
    Guo, Yuzhu
    Guo, Xinyu
    Ge, Kunyang
    Li, Dan
    You, Fangtian
    He, Zhiqun
    SCIENCE CHINA-CHEMISTRY, 2025, 68 (01) : 163 - 173
  • [27] Constructing a Stable and Efficient Buried Heterojunction via Halogen Bonding for Inverted Perovskite Solar Cells
    Zhang, Caiyi
    Shen, Xiangqian
    Chen, Mengjiong
    Zhao, Yan
    Lin, Xuesong
    Qin, Zhenzhen
    Wang, Yanbo
    Han, Liyuan
    ADVANCED ENERGY MATERIALS, 2023, 13 (02)
  • [28] Suppressing Nickel Oxide/Perovskite Interface Redox Reaction and Defects for Highly Performed and Stable Inverted Perovskite Solar Cells
    Ahmad, Sajjad
    Ma, Ruiman
    Zheng, Jiawei
    Kwok, Cheuk Kai Gary
    Zhou, Qisen
    Ren, Zhenwei
    Kim, Jinwook
    He, Xinjun
    Zhang, Xiaoliang
    Yu, Kin Man
    Choy, Wallace C. H.
    SMALL METHODS, 2022, 6 (10):
  • [29] Dimensional Engineering in Efficient and Stable Inverted Perovskite Solar Cells
    Zhu, Qing
    Yu, Yue
    Liu, Xinxing
    He, Dongmei
    Shai, Xuxia
    Feng, Jing
    Yi, Jianhong
    Chen, Jiangzhao
    SOLAR RRL, 2024, 8 (17):
  • [30] Interfacial Modification of NiOx for Highly Efficient and Stable Inverted Perovskite Solar Cells
    Zhou, Yu
    Huang, Xiaozhen
    Zhang, Jinsen
    Zhang, Lin
    Wu, Haotian
    Zhou, Ying
    Wang, Yao
    Wang, Yang
    Fu, Weifei
    Chen, Hongzheng
    ADVANCED ENERGY MATERIALS, 2024, 14 (25)