Rheological properties of graphene oxide/polyamide 6 composites

被引:3
作者
Liao, Haoran [1 ]
Yu, Tao [1 ,2 ,3 ]
Li, Yan [1 ]
机构
[1] Tongji Univ, Sch Aerosp Engn & Appl Mech, Shanghai, Peoples R China
[2] Tongji Univ, Shanghai Key Lab Space Mapping & Remote Sensing Pl, Shanghai, Peoples R China
[3] Tongji Univ, Sch Aerosp Engn & Appl Mech, Shanghai 200092, Peoples R China
基金
中国国家自然科学基金;
关键词
nanocomposites; nylon; rheology; NANOCOMPOSITES; OXIDE;
D O I
10.1002/pc.27729
中图分类号
TB33 [复合材料];
学科分类号
摘要
In this work, graphene oxide (GO)/polyamide 6 (PA6) nanocomposites with different graphene content (0.03-0.5 wt%) were prepared via in situ polymerization of GO and e-caprolactam. The linear and nonlinear rheological properties and thixotropy of GO/PA6 nanocomposites are investigated using steady state, dynamic, and transient rheological method with a Haake plate rotary rheometer. Cox/Merz rules and Cross model were used to fit the shear rate sweep and dynamic frequency sweep data, and a wider range(10(-2)-10(4) s(-1)) of flow curve was obtained. The results show the PA6 and GO/PA6 melts are shear thinning fluid without yield stress, and have thixotropy. Highlights . Dynamic, steady, and transient rheological tests were performed. . Cox/Merz rules and Cross model were used to fit the data. . A wider range(10(-2)-104 s(-1)) of flow curve was obtained.
引用
收藏
页码:8683 / 8692
页数:10
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共 19 条
  • [11] Rheology and 3D Printability of Percolated Graphene-Polyamide-6 Composites
    Lee, Kok Peng Marcian
    Brandt, Milan
    Shanks, Robert
    Daver, Fugen
    [J]. POLYMERS, 2020, 12 (09) : 1 - 15
  • [12] Enhanced thermal-conductive and anti-dripping properties of polyamide composites by 3D graphene structures at low filler content
    Li, Xuheng
    Shao, Linbo
    Song, Na
    Shi, Liyi
    Ding, Peng
    [J]. COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2016, 88 : 305 - 314
  • [13] The rheology of two-phase magmas: A review and analysis
    Mader, H. M.
    Llewellin, E. W.
    Mueller, S. P.
    [J]. JOURNAL OF VOLCANOLOGY AND GEOTHERMAL RESEARCH, 2013, 257 : 135 - 158
  • [14] Improved Synthesis of Graphene Oxide
    Marcano, Daniela C.
    Kosynkin, Dmitry V.
    Berlin, Jacob M.
    Sinitskii, Alexander
    Sun, Zhengzong
    Slesarev, Alexander
    Alemany, Lawrence B.
    Lu, Wei
    Tour, James M.
    [J]. ACS NANO, 2010, 4 (08) : 4806 - 4814
  • [15] Preparation and properties of polyamide 6 nanocomposites covalently linked with amide functional graphene oxide
    O'Neill, Aidan
    Bishop, David
    Dalton, Brendan
    Archer, Edward
    McIlhagger, Alistair
    Dixon, Dorian
    [J]. JOURNAL OF THERMOPLASTIC COMPOSITE MATERIALS, 2018, 31 (02) : 162 - 180
  • [16] Preparation and properties of nylon 6/sulfonated graphene composites by an in situ polymerization process
    Wang, Chunhua
    Hu, Feng
    Yang, Kejian
    Hu, Tianhui
    Wang, Wenzhi
    Deng, Rusheng
    Jiang, Qibin
    Zhang, Hailiang
    [J]. RSC ADVANCES, 2016, 6 (51) : 45014 - 45022
  • [17] Parameter determination for the Cross rheology equation and its application to modeling non-Newtonian flows using the WC-MPS method
    Xie, Jun
    Jin, Yee-Chung
    [J]. ENGINEERING APPLICATIONS OF COMPUTATIONAL FLUID MECHANICS, 2016, 10 (01) : 111 - 129
  • [18] In situ Polymerization Approach to Graphene-Reinforced Nylon-6 Composites
    Xu, Zhen
    Gao, Chao
    [J]. MACROMOLECULES, 2010, 43 (16) : 6716 - 6723
  • [19] Preparation and Characterization of Polyamide-6/Reduced Graphene Oxide Composite Microspheres
    Zhang, Na
    Zhao, Xingke
    Fu, Xubing
    Zhao, Dajiang
    Yang, Guisheng
    [J]. CHEMISTRYSELECT, 2019, 4 (38): : 11294 - 11301