Comparative evaluation of the carbonyl index of microplastics around the Japan coast

被引:29
作者
Celik, Murat [1 ]
Nakano, Haruka [1 ,2 ]
Uchida, Keiichi [1 ]
Isobe, Atsuhiko [2 ]
Arakawa, Hisayuki [1 ]
机构
[1] Tokyo Univ Marine Sci & Technol, 4-5-7 Konan,Minato Ku, Tokyo 1088477, Japan
[2] Kyushu Univ, Res Inst Appl Mech, 6-1 Kasuga Koen, Kasuga, Fukuoka 8168580, Japan
基金
日本科学技术振兴机构;
关键词
Microplastic; Fourier Transform Infrared Spectroscopy; Carbonyl index; Polyethylene; Polypropylene; HIGH-DENSITY POLYETHYLENE; MARINE-ENVIRONMENT; PLASTIC DEBRIS; DEGRADATION; STEARATE; WASTE; FATE; SEA;
D O I
10.1016/j.marpolbul.2023.114818
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The carbonyl index (CI) of polyethylene and polypropylene microplastics (MPs) (2950 particles) collected in coastal waters around Japan was investigated. The CI of MPs was calculated by the specified area under band technique. The mean MP CI in all samples (regardless of shape and color) was 0.69 & PLUSMN; 0.34 and 0.70 & PLUSMN; 0.34 for polyethylene and polypropylene, respectively, and there was no significant difference in the color or shape of the MPs. The polyethylene, white, and fragment MPs CI was negatively (p < 0.05) correlated with the major length of the MPs. Large MPs with relatively little deterioration were distributed along the west coast of the Sea of Japan, whereas small MPs were distributed along the east coast. Our findings of this gradual change in the deterioration of MPs, based on geographical distribution, are in accordance with literature CI-size and MP degradation hypotheses.
引用
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页数:8
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