Synthesis of new ferrocenyl-containing tertiary alcohols, analogs of l-prolinol-based organocatalysts

被引：1

作者：

Burlutsky, Roman O. ^{[1
]}

Yudina, Ella S. ^{[1
]}

Churakov, Andrei, V ^{[2
]}

Lemenovskiy, Dmitriy A. ^{[1
]}

Dyadchenko, Victor P. ^{[1
]}

机构：

[1] M V Lomonosov Moscow State Univ, Dept Chem, Moscow 119991, Russia

[2] Russian Acad Sci, N S Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

MENDELEEV COMMUNICATIONS | 2024年 / 34卷 / 01期

关键词：

asymmetric organocatalysis; ferrocene; proline; tert-butoxycarbonyl protective group; ferrocenylmagnesium bromide; chiral tertiary alcohols; X-ray molecular structure; ENANTIOSELECTIVE SYNTHESIS; DERIVATIVES; CATALYSTS;

D O I：

10.1016/j.mencom.2024.01.019

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Syntheses of new ferrocenyl-containing tertiary alcohols derived from l-proline were developed. In these alcohols, two ferrocenyl groups are bonded at prolinol moiety directly or through p-phenylene spacer. Specific features for the ferrocene Grignard reagents were discovered.

引用

页码：64 / 66

页数：3

共 4 条

[1] Synthesis, structure and catalytic activity of new ferrocenyl-containing secondary alcohols derived from l-proline
Burlutsky, Roman O.
Yudina, Ella S.
Churakov, Andrei, V
Lemenovskiy, Dmitriy A.
Dyadchenko, Victor P.
MENDELEEV COMMUNICATIONS, 2024, 34 (02) : 201 - 203
[2] The synthesis and structure of new tin(II) complexes based on ferrocenyl-containing o-iminophenols
Baryshnikova, S. V.
Bellan, E. V.
Poddel'sky, A. I.
Fukin, G. K.
Abakumov, G. A.
INORGANIC CHEMISTRY COMMUNICATIONS, 2016, 69 : 94 - 97
[3] The synthesis, structure and electrochemical properties of new cobalt and nickel complexes based on ferrocenyl-containing o-iminophenols
Baryshnikova, S. V.
Poddel'sky, A. I.
Cherkasov, A. V.
Smolyaninov, I. V.
INORGANICA CHIMICA ACTA, 2019, 495
[4] The synthesis and structure of new ferrocenyl-containing o- iminophenol schiff bases and nickel(II), copper(II) bis-o- iminophenolato complexes
Baryshnikova, Svetlana, V
Fukin, Georgy K.
Poddel'sky, Andrey, I
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2020, 923

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