Triple-Decker Iron and Cobalt Complexes Featuring a Bridging 1,2-Diboratabenzene Ligand

被引：2

作者：

Tamizmani, Masilamani ^{[1
]}

Tidwell, John R. ^{[1
]}

Reinheimer, Eric W. ^{[2
]}

Lindley, Brian M. ^{[1
]}

Martin, Caleb D. ^{[1
]}

机构：

[1] Baylor Univ, Dept Chem & Biochem, Waco, TX 76798 USA

[2] Rigaku Amer Corp, The Woodlands, TX 77381 USA

来源：

INORGANIC CHEMISTRY | 2023年 / 62卷 / 19期

基金：

美国国家科学基金会;

关键词：

HALF-SANDWICH COMPLEXES; HYPOELECTRONIC RHENABORANES; ELECTRONIC-STRUCTURES; 1,2-DIBORABENZENE; ELECTROCHEMISTRY; POLYMERIZATION; DERIVATIVES; REACTIVITY; ASTERISK; CRYSTAL;

D O I：

10.1021/acs.inorgchem.3c00558

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Neutral triple-decker iron and cobalt complexes with a bridging 1,2-diboratabenzene ligand were accessed by reactions of a dilithium 1,2-diboratabenzene reagent with [Cp*FeCl]2 and [Cp*CoCl]2, respectively. While 1,2-diboratabenzene metal complexes are known, these represent the first examples of the ligand bridging two metals.

引用

页码：7150 / 7154

页数：5

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