Electrochemical characterization of Fe-Mn-Al-Ni shape memory alloy in an alkaline solution contaminated with Cl- ions

被引:6
作者
Frenck, Johanna-Maria [1 ]
Link, Janna [1 ,2 ]
Vollmer, Malte [1 ]
Niendorf, Thomas [1 ]
机构
[1] Univ Kassel, Inst Mat Engn, Moenchebergstr 3, D-34125 Kassel, Germany
[2] Univ Kassel, Dept Struct Mat & Construct Chem, Moenchebergstr 7, D-34125 Kassel, Germany
关键词
Shape memory alloy; Fe-Mn-Al-Ni; Passive behavior; Pitting corrosion; NaCl; KOH;
D O I
10.1016/j.matlet.2023.134457
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In the present work electrochemical corrosion properties of Fe-Mn-Al-Ni in different electrolytic solutions have been investigated by determining the open circuit potential and by conducting potentiodynamic polarization measurements. The corrosion experiments reveal that the exposure to a solution with a high pH (=13.3) results in a passive behavior. However, after adding Cl- ions to the solution, the corrosion behavior changes from passivating to non-passivating. Optical microscopy images further reveal that, independent from the electrolytic solution, selective corrosion of the beta-Mn-phase or the gamma'-phase occurs.
引用
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页数:4
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