Optimizing hydrogen production from alkali hydrides using supported metal catalysts

被引:6
|
作者
Karabulut, Abdurrahman [1 ]
Izgi, M. Sait [1 ]
Demir, Halil [1 ]
Sahin, Oemer [2 ]
Horoz, Sabit [3 ]
机构
[1] Siirt Univ, Fac Engn, Dept Chem Engn, Siirt, Turkiye
[2] Istanbul Tech Univ, Fac Engn, Dept Chem Engn, Istanbul, Turkiye
[3] Sivas Univ Sci & Technol, Fac Engn & Nat Sci, Dept Met & Mat Engn, Sivas, Turkiye
关键词
Hydrogen production; Alkali hydrides; Supported metal catalysts; Co-B@GO; Activation energy; SODIUM-BOROHYDRIDE NABH4; CO-B; HYDROLYSIS; GENERATION; NANOPARTICLES; METHANOLYSIS; BEHAVIOR; COMPLEX;
D O I
10.1007/s11581-023-04962-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The present study aimed to investigate the effect of different parameters on the hydrogen production rate (HPR) during KBH4 hydrolysis using Co-B (pure) and Co-B@GO (supported) catalysts. The results showed that the HPR value for Co-B@GO catalyst was 2299.81 mL*gcat-1 min-1, which was approximately 2.3 times higher than that of the Co-B catalyst (1012.71 mLgcat-1 *min-1). The activation energy of Co-B@GO was also calculated to be 21.62 kJ/mol, lower than some reported values in the literature. This demonstrates the potential of Co-B@GO as a cost-effective and efficient catalyst for hydrogen production from alkali hydrides. The results of this study provide novel insights into the optimization of hydrogen production processes using supported metal catalysts.
引用
收藏
页码:1975 / 1982
页数:8
相关论文
共 50 条
  • [31] Production of hydrogen by ammonia decomposition over supported Co3O4 catalysts
    Li, Guoru
    Yu, Xiaoting
    Yin, Fengxiang
    Lei, Zhiping
    Zhang, Houfu
    He, Xiaobo
    CATALYSIS TODAY, 2022, 402 : 45 - 51
  • [32] Preparation of Silicon Carbide Supported Iron Catalysts and their Catalytic Activities in Hydrogen Production by Ammonia Decomposition
    Liu, Yulian
    Yin, Fengxiang
    Li, Guoru
    Tan, Yuhang
    CATALYSIS LETTERS, 2025, 155 (01)
  • [33] Engineering morphologies of yttrium oxide supported nickel catalysts for hydrogen production
    Zhang, Rong-Bin
    Tu, Zi-Ao
    Meng, Shuai
    Feng, Gang
    Lu, Zhang-Hui
    Yu, Ying-Zhi
    Reina, Tomas Ramirez
    Hu, Fei-Yang
    Chen, Xiao-Han
    Ye, Run-Ping
    RARE METALS, 2023, 42 (01) : 176 - 188
  • [34] On-demand Hydrogen Production from Organosilanes at Ambient Temperature Using Heterogeneous Gold Catalysts
    Mitsudome, Takato
    Urayama, Teppei
    Kiyohiro, Taizo
    Maeno, Zen
    Mizugaki, Tomoo
    Jitsukawa, Koichiro
    Kaneda, Kiyotomi
    SCIENTIFIC REPORTS, 2016, 6
  • [35] COx-free hydrogen production from ammonia on novel cobalt catalysts supported on 1D titanate nanotubes
    Lara-Garcia, Hugo A.
    Arturo Mendoza-Nieto, J.
    Pfeiffer, Heriberto
    Torrente-Murciano, Laura
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (57) : 30062 - 30074
  • [36] Polymer hydrogel supported Pd-Ni-B nanoclusters as robust catalysts for hydrogen production from hydrolysis of sodium borohydride
    Liu, Wenyu
    Cai, Haokun
    Lu, Ping
    Xu, Qiumei
    Zhongfu, Yafeng
    Dong, Jian
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (22) : 9206 - 9216
  • [37] Production of hydrogen from magnesium hydrides hydrolysis
    Tayeh, T.
    Awad, A. S.
    Nakhl, M.
    Zakhour, M.
    Silvain, J. -F.
    Bobet, J. -L.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (07) : 3109 - 3117
  • [38] Transition Metal Oxides as Catalysts for Hydrogen Production from Supercritical Water Gasification of Glucose
    Cao, Changqing
    Zhang, Yi
    Cao, Wen
    Jin, Hui
    Guo, Liejin
    Huo, Ziyang
    CATALYSIS LETTERS, 2017, 147 (04) : 828 - 836
  • [39] Ultrahigh figure-of-merit for hydrogen generation from sodium borohydride using ternary metal catalysts
    Hu, Lunghao
    Ceccato, R.
    Raj, R.
    JOURNAL OF POWER SOURCES, 2011, 196 (01) : 69 - 75
  • [40] Efficient production of hydrogen from formic acid using a Covalent Triazine Framework supported molecular catalyst
    Bavykina, A. V.
    Goesten, M. G.
    Kapteijn, F.
    Makkee, M.
    Gascon, J.
    CHEMSUSCHEM, 2015, 8 (05) : 809 - 812