Three New Lanthanum Oxoantimonate(III) Halides: Synthesis and Crystal Structure of La5Cl3[SbO3]4, La2Sb12O19Br4 and La2Sb12O19I4

被引：2
作者：
Locke, Ralf J. C. [1 ]
Bozenhardt, Kim-Natalie [1 ]
Goerigk, Felix C. [1 ,2 ]
Schleid, Thomas [1 ]
机构：
[1] Univ Stuttgart, Inst Inorgan Chem, D-70569 Stuttgart, Germany
[2] Leuchtstoffwerk Breitungen GmbH, D-98597 Breitungen, Germany
来源：
CRYSTALS | 2023年 / 13卷 / 05期
关键词：
lanthanum; oxoantimonates(III); halides; crystal structures; Raman spectra; ANTIMONY(III) OXIDE IODIDE; SINGLE-CRYSTAL; ONORATOITE; REFINEMENT; TRIOXIDE; POLYTYPE;
D O I：
10.3390/cryst13050731
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
It was possible to synthesize colorless single crystals of La5Cl3[SbO3](4) (block-shaped) as well as La2Sb12O19Br4 and La2Sb12O19I4 (both needle-shaped), representing three new compounds from the system of lanthanum oxoantimonate(III) halides, which have not been described in the literature before. La5Cl3[SbO3](4) crystallizes in the monoclinic space group P2/c with the lattice parameters a = 895.82(5) pm, b = 564.28(3) pm, c = 1728.19(9) pm, and beta 3 = 90.007(2)degrees for Z = 2. This layered compound contains isolated psi(1)-tetrahedral [SbO3](3-) units, square hemiprisms [LaO8](13-), and antiprisms [LaO4Cl4](9-). La2Sb12O19Br4 and La2Sb12O19I4 crystallize isotypically in the orthorhombic space group Pnma with a = 3184.69(19) pm, b = 417.78(3) pm, c = 1019.85(6) pm for the bromide and a = 3215.08(19) pm, b = 419.94(3) pm, c = 1062.89(6) pm for the iodide. Instead of isolated [SbO3](3-) anions, semi-tubular features (1)(infinity){[Sb12O19](2-)} are present, which consist mainly of [SbO4](5-) and few [Sb03]3- units with stereochemically active electronic lone pairs at their Sb3+ centers. Within these socalled "double-halfpipes", La3+ is surrounded by nine oxygen atoms as [LaO9](15-) polyhedron without any contact with X- anions. Single -crystal Raman measurements were performed for La5Cl3[SbO3](4) and La2Sb12O19I4, and La5Cl3[SbO3](4) was structurally compared with the isostoichiometric, but not isotypic La5F3[SFO3](4).
引用
收藏
页数：20
相关论文
共 50 条
  • [21] SYNTHESIS, STRUCTURE, AND PROPERTIES OF THE NOVEL BROMOSELENATES(II) [SE3BR8]2-, [SE4BR14]2-, AND [SE5BR12]2- - CRYSTAL-STRUCTURES OF [CU(I-PROPCN)4]2[SE3BR8], [ETPH3P]2[SE4BR14], AND [N-PROP4N]2[SE5BR12]
    KREBS, B
    AHLERS, FP
    LUHRS, E
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1991, 597 (06): : 115 - 132
  • [22] Framework compounds with mobile LaIII cations:: Syntheses, crystal structures and structural dynamics of the Lanthanum(III) Iron(II) sulfide halides La53Fe12S90X3 (X=Cl, Br, I)
    Braeunling, Daniel
    Leoni, Stefano
    Mills, Allison M.
    Ruck, Michael
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2008, 634 (01): : 107 - 114
  • [23] Synthesis, Crystal Structure, and Photoluminescent and Semiconductive Properties of [La(C6NO2H5)3(H2O)2]2n•(nH5O2)(nHgCl5)(2nHgCl4)•(2nH2O)
    Chen Wen-Tong
    Huang Jin-Shun
    Liu Dong-Sheng
    Liu Jiu-Hui
    Ying Shao-Ming
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 27 (11) : 1299 - 1304
  • [24] Synthesis and characterization of heteronuclear germanium(IV) and lanthanum(III) (chromium(III)) complexes with 1,3-diamino-2-propanoltetraacetic acid: Crystal and molecular structure of [Ge(OH)(μ-Hpdta)(μ-OH)La(H2O)4] · H2O
    I. I. Seifullina
    L. Kh. Minacheva
    V. S. Sergienko
    E. E. Martsinko
    Russian Journal of Inorganic Chemistry, 2012, 57 : 658 - 664
  • [25] Syntheses, crystal structures and magnetic properties of heterometallic copper-lanthanide clusters [Cu12Ln6(μ3-OH)24(μ-O2CR)12(H2O)18(μ12-ClO4)]5+ (Ln = La, Nd; R = CH2Cl, CCl3)
    Cui, Y
    Chen, JT
    Huang, JS
    INORGANICA CHIMICA ACTA, 1999, 293 (02) : 129 - 139
  • [26] Synthesis,Crystal Structure,and Photoluminescent and Semiconductive Properties of [La(C6NO2H5)3-(H2O)2]2n·(nH5O2)(nHgCl5)(2nHgCl4)·(2nH2O)
    陈文通
    黄锦顺
    刘冬生
    刘九辉
    应少明
    结构化学, 2008, (11) : 1299 - 1304
  • [27] Rare-earth-metal coordination polymers:: Synthesis and crystal structures of five new adipinates, [M2(Adi)3(H2O)4](AdiH2)(H2O)4 (M = La, Nd), [Er(Adi)(H2O)5]Cl(H2O) and [M(Adi)(H2O)5](NO3)(H2O) (M = Gd, Er)
    Bromant, C
    Flemig, H
    Nika, W
    Pantenburg, I
    Meyer, G
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (05): : 851 - 858
  • [28] Hydrothermal synthesis and characterization of a Na+ templated new 3-D lanthanum sulfate Na[C6H14N2][La3(SO4)6(H2O)3] constructed from La-O-S tubes and cubic cages
    Zheng, Lei
    Zhang, Zhibin
    Zhu, Dunru
    Xu, Yan
    INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (01) : 258 - 260
  • [29] New inorganic ligand μ3-[SbO(H2O)2]3- in tetrahedral mixed-ligand rhenium cluster complexes K5[{Re4Q3[SbO(H2O)2]}(CN)12] (Q = S, Se)
    Pronin, A. S.
    Mironov, Y., V
    RUSSIAN CHEMICAL BULLETIN, 2022, 71 (10) : 2179 - 2186
  • [30] Na2La4(NH2)14•NH3, a lanthanum-rich intermediate in the ammonothermal synthesis of LaN and the effect of ammonia loss on the crystal structure
    Kunkel, Sebastian
    Niewa, Rainer
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2021, 76 (10-12): : 567 - 575
12345