Electrocatalytic Properties of Co3O4 Prepared on Carbon Fibers by Thermal Metal-Organic Deposition for the Oxygen Evolution Reaction in Alkaline Water Electrolysis

Cobalt oxide (Co3O4) serves as a promising electrocatalyst for oxygen evolution reactions (OER) in water-electrolytic hydrogen production. For more practical applications, advances in dry-deposition processes for the high-throughput fabrication of such Co3O4 electrocatalysts are needed. In this work, a thermal metal-organic deposition (MOD) technique is developed to form Co3O4 deposits on microscale-diameter carbon fibers constituting a carbon fiber paper (CFP) substrate for high-efficiency OER electrocatalyst applications. The Co3O4 electrocatalysts are deposited while uniformly covering the surface of individual carbon fibers in the reaction temperature range from 400 to 800 degrees C under an ambient Ar atmosphere. It is found that the microstructure of deposits is dependent on the reaction temperature. The Co3O4 electrocatalysts prepared at 500 degrees C and over exhibit values of 355-384 mV in overpotential (eta(10)) required to reach a current density of 10 mA cm(-2) and 70-79 mV dec(-1) in Tafel slope, measured in 1 M KOH aqueous solution. As a result, it is highlighted that the improved crystallinity of the Co3O4 electrocatalyst with the increased reaction temperature leads to an enhancement in electrode-level OER activity with the high electrochemically active surface area (ECSA), low charge transfer resistance (R-ct), and low eta(10), due to the enhanced electrical conductivity. On the other hand, it is found that the inherent catalytic activity of the surface sites of the Co3O4, represented by the turnover frequency (TOF), decreases with reaction temperature due to the high-temperature sintering effect. This work provides the groundwork for the high-throughput fabrication and rational design of high-performance electrocatalysts.