Revealing the order-disorder type phase transition mechanism in two new supramolecular clathrates

被引：0
作者：
Wei, Wen-Juan [1 ,2 ]
Gao, Hong-Qiang [1 ,2 ]
Fang, Ming [1 ,2 ]
Tang, Yun-Zhi
Wei, Yen [1 ,2 ]
机构：
[1] Tsinghua Univ, Tsinghua Ctr Frontier Polymer Res, Dept Chem, Beijing 100084, Peoples R China
[2] Jiangxi Univ Sci & Technol, Fac Mat Met & Chem, Ganzhou 341000, Peoples R China
来源：
CRYSTENGCOMM | 2023年 / 25卷 / 09期
基金：
中国国家自然科学基金;
关键词：
MOLECULAR ROTORS; DYNAMICS; MOTION;
D O I：
10.1039/d2ce01419j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Phase transition materials can be applied for energy storage or environmental temperature control due to their characteristic of releasing or absorbing a large amount of heat near phase transition temperature. Herein, two new supramolecular-based compounds [(NRT)-(18-crown-6)][ClO4] and [(NRT)-(18-crown-6)][BF4] (1 and 2) have been constructed and their phase transitions were systematically characterized by DSC, variable temperature single-crystal/powder X-ray analysis and Raman spectroscopy.
引用
收藏
页码：1333 / 1338
页数：6
相关论文
共 50 条
  • [31] Order-disorder transition of intrinsically disordered kinase inducible transactivation domain of CREB
    Liu, Hao
    Guo, Xiang
    Han, Jingcheng
    Luo, Ray
    Chen, Hai-Feng
    JOURNAL OF CHEMICAL PHYSICS, 2018, 148 (22)
  • [32] Order-disorder transition and flow noise in an a-MoxGe1-x film
    Okuma, S.
    Suzuki, Y.
    Kokubo, N.
    PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS, 2009, 469 (15-20): : 1096 - 1098
  • [33] Order-disorder phase transitions in front of the exit during human crowd evacuations
    Yi, Wenfeng
    Wu, Wenhan
    Wang, Xiaolu
    Wang, Erhui
    Zheng, Xiaoping
    TRANSPORTATION RESEARCH PART C-EMERGING TECHNOLOGIES, 2024, 163
  • [34] Order-disorder behavior in the ferroelectric nematic phase investigated via Raman spectroscopy
    Raistrick, Thomas
    Mandle, Richard J.
    Zhang, Zhaopeng
    Tipping, Peter J.
    Gleeson, Helen F.
    PHYSICAL REVIEW E, 2024, 110 (04)
  • [35] Order-Disorder Transition of Dipolar Rotor in a Crystalline Molecular Gyrotop and Its Optical Change
    Setaka, Wataru
    Yamaguchi, Kentaro
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (39) : 14560 - 14563
  • [36] The Impact of Polydispersity and Molecular Weight on the Order-Disorder Transition in Poly(3-hexylthiophene)
    Panzer, Fabian
    Baessler, Heinz
    Lohwasser, Ruth
    Thelakkat, Mukundan
    Koehler, Anna
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2014, 5 (15): : 2742 - 2747
  • [37] Crystals of Charge-Transfer Complexes with Reorienting Polar Molecules: Dielectric Properties and Order-Disorder Phase Transitions
    Harada, Jun
    Yoneyama, Naho
    Sato, Shota
    Takahashi, Yukihiro
    Inabe, Tamotsu
    CRYSTAL GROWTH & DESIGN, 2019, 19 (01) : 291 - 299
  • [38] Landau theory for stress-induced order-disorder transitions in phase change materials
    Thielen, Matthias
    Nistor, Razvan A.
    Shakhvorostov, Dmitryi
    Beltramo, Guillermo
    Giesen, Margret
    Mueser, Martin H.
    PHYSICAL REVIEW B, 2014, 89 (05):
  • [39] Defect Removal in the Course of Directed Self-Assembly is Facilitated in the Vicinity of the Order-Disorder Transition
    Li, Weihua
    Nealey, Paul F.
    de Pablo, Juan J.
    Mueller, Marcus
    PHYSICAL REVIEW LETTERS, 2014, 113 (16)
  • [40] Order-Disorder Transition of Nanocomposites: Polystyrene-block-Poly(methyl methacrylate) with Palladium Nanoparticles
    Zhao, Yue
    Saijo, Kenji
    Hashimoto, Takeji
    MACROMOLECULES, 2013, 46 (03) : 957 - 970
12345