A dinuclear copper(ii) complex with photoswitchable catechol oxidation activity

被引:8
作者
Marcon, Michela [1 ]
Crespi, Stefano [2 ]
Pielmeier, Andreas [1 ]
Koenig, Burkhard [1 ]
机构
[1] Univ Regensburg, Fac Chem & Pharm, Univ Str 31, D-93053 Regensburg, Germany
[2] Uppsala Univ, Dept Chem, Angstrom Labs, Box 523, S-75120 Uppsala, Sweden
基金
瑞典研究理事会;
关键词
OXIDASE;
D O I
10.1039/d2cc06250j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this study, we report the first example of a photoswitchable copper complex with catechol oxidase activity. The distance between the two copper centres is optimal for catalytic catechol oxidation in the Z-configuration. Thus, the activity of the catalyst is increased compared to its E-configuration.
引用
收藏
页码:948 / 951
页数:4
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