Studies on crystal structures, optical, dyeing and biological properties of protoberberine alkaloids and their supramolecular salts

被引：3

作者：

Du, Haijuan ^{[1
]}

Hao, Keqian ^{[1
]}

Wang, Qi ^{[2
]}

Huang, Xin ^{[1
]}

Wu, Jie ^{[2
]}

Li, Hongyun ^{[2
]}

Huang, Chunyue ^{[1
]}

Xu, Lang ^{[1
]}

Yin, Li ^{[1
]}

Lin, Jiao ^{[1
]}

机构：

[1] Zhongyuan Univ Technol, Coll Text, Zhengzhou 450007, Peoples R China

[2] Zhengzhou Univ, Affiliated Hosp 5, Dept Resp & Crit Care Med, Zhengzhou 450054, Peoples R China

来源：

BIOORGANIC CHEMISTRY | 2023年 / 130卷

关键词：

Palmatine (PLT); Optical characteristics; Dyeing properties; Toxicity; 5-SULFOSALICYLIC ACID; PALMATINE; BERBERINE; BINDING; FORMS; TRANSFORMATIONS; DERIVATIVES; SOLUBILITY; COMPLEXES; DNA;

D O I：

10.1016/j.bioorg.2022.106256

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The novel Palmatine (PLT)-based supramolecular salt palmatine-sulfosalicylic acid (PLT-SSA) was designed and synthesized, and its structures was determined by the single crystal X-ray diffraction. It is found that PLT-SSA exhibited enhancing thermodynamic stability, fluorescence intensity and emission lifetime in crystal state, which indicated that these structures and aromatic rings may give more overlap between the host-guest units and give rise to a long-lived charge-separated state. In addition, the dyeing properties and toxicity of these protoberberine alkaloid (BBC and PLTCl) and their supramolecular salts will be developed in this work used as yellow dyes for development multifunctional fabrics.

引用

页数：7

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