Rapid, Mild, and Catalytic Synthesis of 2D and 3D COFs with Promising Supercapacitor Applications

被引:20
作者
Khojastehnezhad, Amir [1 ]
Rhili, Khaled [1 ]
Shehab, Mohammad [2 ]
Gamraoui, Hichem [1 ]
Peng, Zhiyuan [1 ]
Samih ElDouhaibi, Ahmad [3 ]
Touzani, Rachid [4 ]
Hammouti, Belkheir [5 ]
El-Kaderi, Hani [2 ]
Siaj, Mohamed [1 ]
机构
[1] Univ Quebec Montreal, Dept Chem, Montreal, PQ H3C 3P8, Canada
[2] Virginia Commonwealth Univ, Dept Chem, Richmond, VA 23284 USA
[3] Lebanese Univ, Coll Sci 3, Dept Chem, Tripoli 1352, Lebanon
[4] Mohammed First Univ, Lab Appl & Environm Chem LCAE, Oujda 60000, Morocco
[5] Euromed Univ Fes, Dept Chem, Fes 30070, Morocco
基金
加拿大自然科学与工程研究理事会; 加拿大创新基金会;
关键词
imine linked-COF; azine-linked COF; triazineCOF; heteropoly acids; Keggin; 2D and 3DCOFs; COVALENT ORGANIC FRAMEWORKS; ROOM-TEMPERATURE; GRAPHENE OXIDE; CRYSTALLINE; NANOSHEETS; NETWORKS; NITROGEN; CARBON;
D O I
10.1021/acsaem.3c01913
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An approach based on Keggin heteropoly acids (HPAs) has been presented for the mild and fast synthesis of five different structures of imine and azine-linked two-dimensional (2D) and three-dimensional (3D) covalent organic frameworks (COFs). Traditionally, these crystalline materials have been synthesized via the Schiff base polycondensation reaction between different aldehydes and amines under harsh conditions and in the presence of acetic acid. Herein, two different Keggin-type heteropolyacids (HPAs) have been exploited as catalysts which are both Bronsted and Lewis acids to speed up the synthesis of 2D and 3D COFs and improve their materials quality. The catalyst led to the preparation of the imine and azine-linked COFs with high crystallinity and porosity under mild conditions and short reaction time. According to the results, the amine building blocks with two amine functional groups formed the COFs with higher crystallinity, porosity, and yield compared to amine with three functional groups and nonplanar structures. On this basis, under mild reaction conditions, a 2D COF named TAPA-TPT was successfully prepared with high crystallinity and good porosity. The developed TAPA-TPT COF exhibits a very good performance when used in supercapacitor applications. This COF showed excellent specific capacitance of 205 F g(-1) at a current density of 0.5 A g(-1), which is a very attractive value for supercapacitors. This study provides a synthetic approach that can lead to large-scale production of COF materials for energy harvesting.
引用
收藏
页码:12216 / 12225
页数:10
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