Sustainable Development of Activated Porous Carbon Materials from Gum Arabic Tree Seed Shell for CO2 Capture

被引:5
作者
Goskula, Srinath [1 ]
Siliveri, Suresh [1 ,2 ]
Gujjula, Sripal Reddy [1 ]
Chirra, Suman [1 ,3 ]
Adepu, Ajay Kumar [1 ,4 ]
Narayanan, Venkatathri [1 ]
机构
[1] Natl Inst Technol, Dept Chem, Warangal 506004, Telangana, India
[2] CMR Coll Engn & Technol, Dept Humanity & Sci, Hyderabad 501401, Telangana, India
[3] Natl Cheng Kung Univ, Dept Chem Engn, Tainan 70101, Taiwan
[4] CSIR Indian Inst Chem Technol, Inorgan & Phys Chem Div, Hyderabad 500007, India
关键词
Biomass; Chemical activation; Carbonization; Carbon adsorbents; CO2; capture; High surface area; KOH; Micropores; Recyclability; HYDROTHERMAL CARBONIZATION; ADSORPTION PROPERTIES; MICROPOROUS CARBONS; BIOMASS; WASTE; ADSORBENTS; PYROLYSIS; DIOXIDE; TEMPERATURE; PERFORMANCE;
D O I
10.1007/s11270-023-06529-9
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Here in this work, gum arabic tree seed shell (bio mass) was utilized to synthesize carbon adsorbents by chemical activation methods at constant carbonization temperature. The properties of the carbon adsorbents were estimated through characterization techniques such as X-ray diffraction, Fourier Transform Infrared spectroscopy, Laser Raman spectroscopy, Field Emission Scanning electron microscopy, CHNS-elemental analysis and N-2 adsorption studies. Gum arabic tree seed shell-derived carbon adsorbents were examined for CO2 capture in 25 to 70 ? temperature range. The characterization results indicated that these carbons contain high surface area with micro porosity. Among all the carbons, the carbon prepared after treatment of KOH to biomass ratio is 3:1 followed by and carbonization at 750 ? exhibited high adsorption capacity of 3.42 m.mol/g at 25 ?. The reason for high adsorption capacity of the adsorbents mainly depended on surface area (1472 m(2)/g) and micropore volume. The adsorbents showed easy desorption and recyclable up to five cycles with consistent activity.
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页数:16
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