Gold-Catalyzed Cross-Coupling and 1,2-Difunctionalization Reactions: A Personal Account

被引:18
作者
Ambegave, Shivhar B. [1 ]
Patil, Nitin T. [1 ]
机构
[1] Indian Inst Sci Educ & Res Bhopal, Dept Chem, Bhopal 462066, India
关键词
biaryls; catalysis; cross-coupling; cyclisation; enantioselectivity; ligands; ALKENYL CARBONYL-COMPOUNDS; I/AU-III CATALYSIS; LIGHT PHOTOREDOX; TERMINAL ALKYNES; UNACTIVATED OLEFINS; ARYLDIAZONIUM SALTS; SELECTIVE SYNTHESIS; DICARBOFUNCTIONALIZATION; CYCLOADDITIONS; CHEMISTRY;
D O I
10.1055/a-1893-7653
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
In recent years, gold catalysis involving Au(I)/Au(III) redox cycle has gained significant attention. This account summarizes our contributions to the development of Au(I)/Au(III) catalysis, focusing on cross-coupling reactions and 1,2-difunctionalization reactions of C-C multiple bonds. A special emphasis has been given to understanding the mechanism of the reactions.
引用
收藏
页码:698 / 708
页数:11
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