Gold-Catalyzed Cross-Coupling and 1,2-Difunctionalization Reactions: A Personal Account

被引:24
作者
Ambegave, Shivhar B. [1 ]
Patil, Nitin T. [1 ]
机构
[1] Indian Inst Sci Educ & Res Bhopal, Dept Chem, Bhopal 462066, India
关键词
biaryls; catalysis; cross-coupling; cyclisation; enantioselectivity; ligands; ALKENYL CARBONYL-COMPOUNDS; I/AU-III CATALYSIS; LIGHT PHOTOREDOX; TERMINAL ALKYNES; UNACTIVATED OLEFINS; ARYLDIAZONIUM SALTS; SELECTIVE SYNTHESIS; DICARBOFUNCTIONALIZATION; CYCLOADDITIONS; CHEMISTRY;
D O I
10.1055/a-1893-7653
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
In recent years, gold catalysis involving Au(I)/Au(III) redox cycle has gained significant attention. This account summarizes our contributions to the development of Au(I)/Au(III) catalysis, focusing on cross-coupling reactions and 1,2-difunctionalization reactions of C-C multiple bonds. A special emphasis has been given to understanding the mechanism of the reactions.
引用
收藏
页码:698 / 708
页数:11
相关论文
共 115 条
[11]   Gold-catalyzed decorations of arenes and heteroarenes with C-C multiple bonds [J].
Bandini, Marco .
CHEMICAL SOCIETY REVIEWS, 2011, 40 (03) :1358-1367
[12]   Gold-Catalyzed Alkynylative Meyer-Schuster Rearrangement [J].
Banerjee, Somsuvra ;
Ambegave, Shivhar B. ;
Mule, Ravindra D. ;
Senthilkumar, Beeran ;
Patil, Nitin T. .
ORGANIC LETTERS, 2020, 22 (12) :4792-4796
[13]   Gold and hypervalent iodine(iii): liaisons over a decade for electrophilic functional group transfer reactions [J].
Banerjee, Somsuvra ;
Bhoyare, Vivek W. ;
Patil, Nitin T. .
CHEMICAL COMMUNICATIONS, 2020, 56 (18) :2677-2690
[14]   Exploiting the dual role of ethynylbenziodoxolones in gold-catalyzed C(sp)-C(sp) cross-coupling reactions [J].
Banerjee, Somsuvra ;
Patil, Nitin T. .
CHEMICAL COMMUNICATIONS, 2017, 53 (56) :7937-7940
[15]   Intramolecular ipso-arylative cyclization of aryl-alkynoates and N-arylpropiolamides with aryldiazonium salts through merged gold/visible light photoredox catalysis [J].
Bansode, Avinash H. ;
Shaikh, Samir R. ;
Gonnade, Rajesh G. ;
Patil, Nitin T. .
CHEMICAL COMMUNICATIONS, 2017, 53 (65) :9081-9084
[16]   Catalytic Branching Cascades in Diversity Oriented Synthesis [J].
Bansode, Avinash H. ;
Chimala, Prathyusha ;
Patil, Nitin T. .
CHEMCATCHEM, 2017, 9 (01) :30-40
[17]   The interplay of carbophilic activation and Au(i)/Au(iii) catalysis: an emerging technique for 1,2-difunctionalization of C-C multiple bonds [J].
Bhoyare, Vivek W. ;
Tathe, Akash G. ;
Das, Avishek ;
Chintawar, Chetan C. ;
Patil, Nitin T. .
CHEMICAL SOCIETY REVIEWS, 2021, 50 (18) :10422-10450
[18]  
Bond GC, 2006, CATALY SCI SER, V6, P1, DOI 10.1142/9781860948954
[19]   Gold-mediated C-H bond functionalisation [J].
Boorman, Tanya C. ;
Larrosa, Igor .
CHEMICAL SOCIETY REVIEWS, 2011, 40 (04) :1910-1925