Heterogeneous geminal-atom catalysis: Cross-coupling reactions through the pair single-atom sites

被引：0
作者：
Min, Xiang-Ting [1 ]
Qiao, Botao [1 ,2 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, CAS Key Lab Sci & Technol Appl Catalysis, Dalian 116023, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
CHEM | 2023年 / 9卷 / 12期
基金：
中国博士后科学基金; 中国国家自然科学基金;
关键词：
CO OXIDATION;
D O I：
10.1016/j.chempr.2023.10.013
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Heterogeneous single-atom catalysts (SACs) have the potential to revolutionize organic synthesis. Recently, in Nature, Lu and co-workers developed geminalatom catalysts (GACs) for catalyzing complex molecular cross-coupling reactions. In this reaction, the co-operativity of metal centers in the geminal sites enabled the efficient activation of substrates through a dynamic bridge-coupling mechanism.
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