Recent progress of composite polyethylene separators for lithium/ sodium batteries

被引:73
作者
Babiker, Dafaalla M. D. [1 ]
Usha, Zubaida Rukhsana [1 ]
Wan, Caixia [1 ]
Hassaan, Mohmmed Mun ELseed [2 ]
Chen, Xin [1 ,3 ]
Li, Liangbin [1 ]
机构
[1] Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Anhui Prov Engn Lab Adv Funct Polymer Film, CAS Key Lab Soft Matter Chem, Hefei 230026, Peoples R China
[2] Chinese Acad Sci, Univ Sci & Technol China, Inst Plasma Phys, Hefei 230026, Peoples R China
[3] Southwest Univ Sci & Technol, Natl Coinnovat Ctr Nucl Waste Disposal & Environm, Mianyang 621010, Peoples R China
基金
国家重点研发计划; 中国国家自然科学基金;
关键词
Lithium -ion batteries; Sodium -ion batteries; Polyolefin separators; Composite separators; Polyethylene separators; Battery safety; CERAMIC-COATED SEPARATORS; CHEMICAL-VAPOR-DEPOSITION; ATOMIC LAYER DEPOSITION; ELECTRON-BEAM IRRADIATION; GEL POLYMER ELECTROLYTES; HIGH-RATE CAPABILITY; LI-ION BATTERIES; HIGH-PERFORMANCE; ELECTROCHEMICAL PERFORMANCE; THERMAL-STABILITY;
D O I
10.1016/j.jpowsour.2023.232853
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Microporous membrane separators (MMS) are at the heart of rechargeable lithium/sodium ion batteries (LIBs/ NIBs) because they prevent short circuits and serve as a channel for ion transport during charge-discharge op-erations. Although the separator is an inactive part of the battery, its structure and properties have a significant impact on the safety, electrochemical performance, and reusability of the battery. This review article summarizes the state-of-the-art fundamental requirements and properties of ideal separators for LIBs and NIBs. Different battery membranes are briefly discussed, including microporous, non-woven, electrolyte, composite, and modified microporous membranes. This paper provides in-depth descriptions of the fabrication and development of hybrid composite separators based on porous polyethylene (PE) membranes for LIBs and NIBs. Furthermore, it discusses advanced battery separators and presents comparative deliberations on various unique preparation processes for high-performance hybrid PE separators. Finally, a brief outlook for future trends in this research area is provided. Insights from such a review article will thereby further assist researchers and developers working on hybrid polyolefin separators towards future battery expansions.
引用
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页数:33
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