Application of nonmetallic frustrated cations in the activation of small molecules

被引：3
作者：
Kaniewska-Laskowska, Kinga [1 ,2 ]
Czapla, Marcin [3 ]
Chojnacki, Jaroslaw [1 ,2 ]
Grubba, Rafal [1 ,2 ]
机构：
[1] Gdansk Univ Technol, Fac Chem, Dept Inorgan Chem, Narutowicza 11-12, PL-80233 Gdansk, Poland
[2] Gdansk Univ Technol, Adv Mat Ctr, Narutowicza 11-12, PL-80233 Gdansk, Poland
[3] Univ Gdansk, Fac Chem, Dept Theoret Chem, Lab Quantum Chem, Wita Stwosza 63, PL-80308 Gdansk, Poland
来源：
DALTON TRANSACTIONS | 2023年 / 52卷 / 24期
关键词：
Boron; Phosphorus; Borinium cations; Frustrated Lewis pairs; Small molecule activation; MAIN-GROUP ELEMENTS; LEWIS PAIRS; BORINIUM; ION; REACTIVITY; CHEMISTRY; BORENIUM; GROUP-4;
D O I：
10.1039/d3dt01433a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The concept of nonmetallic frustrated cations has been used in the small molecule activation. The in situ generated ambiphilic phosphinoborinium cation activated phenyl isocyanate, diisopropylcarbodiimide, and acetonitrile under very mild conditions without any catalyst, yielding single-, double-, or mixed-activation products. Furthermore, the mechanisms of the reactions of the phosphinoborinium cation with small molecules were elucidated using density functional theory calculations.
引用
收藏
页码：8311 / 8315
页数：5
相关论文
共 43 条
[1]   Insertion reactions of the C-B-N-substituted borinium cation [MesBNiPr2]+ [J].
Bamford, Karlee L. ;
Stephan, Douglas W. .
DALTON TRANSACTIONS, 2020, 49 (48) :17571-17577
[2]   Activation of H2 and Et3SiH by the Borinium Cation [Mes2B]+: Avenues to Cations [MesB(μ-H)2(μ-Mes)BMes]+ and [H2B(μ-H)(μ-Mes)B(μ-Mes)(μ-H)BH2]+ [J].
Bamford, Karlee L. ;
Qu, Zheng-Wang ;
Stephan, Douglas W. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (15) :6180-6184
[3]   Main-Group Metallomimetics: Transition Metal-like Photolytic CO Substitution at Boron [J].
Braunschweig, Holger ;
Krummenacher, Ivo ;
Legare, Marc-Andre ;
Matler, Alexander ;
Radacki, Krzysztof ;
Ye, Qing .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (05) :1802-1805
[4]   Reactivity of Phosphaboradibenzofulvene toward Hydrogen, Acetonitrile, Benzophenone, and 2,3-Dimethylbutadiene [J].
Breunig, Jens Michael ;
Huebner, Alexander ;
Bolte, Michael ;
Wagner, Matthias ;
Lerner, Hans-Wolfram .
ORGANOMETALLICS, 2013, 32 (22) :6792-6799
[5]   Dinitrogen activation by group 4 and group 5 metal complexes supported by phosphine-amido containing ligand manifolds [J].
Burford, Richard J. ;
Yeo, Alyssa ;
Fryzuk, Michael D. .
COORDINATION CHEMISTRY REVIEWS, 2017, 334 :84-99
[6]   Cationic Group 4 Metallocene-(o-Phosphanylaryl)oxido Complexes: Synthetic Routes to Transition-Metal Frustrated Lewis Pairs [J].
Chapman, Andy M. ;
Haddow, Mairi F. ;
Wass, Duncan F. .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012, (09) :1546-1554
[7]   Frustrated Lewis Pairs beyond the Main Group: Synthesis, Reactivity, and Small Molecule Activation with Cationic Zirconocene-Phosphinoaryloxide Complexes [J].
Chapman, Andy M. ;
Haddow, Mairi F. ;
Wass, Duncan F. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (45) :18463-18478
[8]   Unraveling the reactivity of a cationic iminoborane: avenues to unusual boron cations [J].
Guo, Rui ;
Zhang, Xin ;
Li, Tong ;
Li, Qianli ;
Ruiz, David A. ;
Liu, Liu Leo ;
Tung, Chen-Ho ;
Kong, Lingbing .
CHEMICAL SCIENCE, 2022, 13 (08) :2303-2309
[9]   Zirconium-Nitrogen Intermolecular Frustrated Lewis Pairs [J].
Hamilton, Hugh B. ;
King, Ashley M. ;
Sparkes, Hazel A. ;
Pridmore, Natalie E. ;
Wass, Duncan F. .
INORGANIC CHEMISTRY, 2019, 58 (09) :6399-6409
[10]   Frustrated Lewis Pair vs Metal-Carbon σ-Bond Insertion Chemistry at an o-Phenylene-Bridged Cp2Zr+/PPh2 System [J].
Jian, Zhongbao ;
Daniliuc, Constantin G. ;
Kehr, Gerald ;
Erker, Gerhard .
ORGANOMETALLICS, 2017, 36 (02) :424-434
12345