Nickel-catalyzed sulfonylative coupling of 2-chlorobenzothiazoles with sulfinates at room temperature

被引：5
作者：
Zhu, Haibo [1 ]
Zhang, Yingying [1 ]
Ren, Gaowen [1 ]
Wang, Yaoqi [1 ]
Meng, Jia [1 ]
Fan, Qiangwen [1 ]
Xie, Zongbo [1 ]
Le, Zhang-Gao [1 ]
机构：
[1] East China Univ Technol, Jiangxi Prov Key Lab Synthet Chem, Nanchang 330013, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 08期
基金：
中国国家自然科学基金;
关键词：
SULFUR-DIOXIDE SURROGATE; O BOND ACTIVATION; ANTIMICROBIAL ACTIVITY; C-S; NI; CONSTRUCTION; SODIUM; ETHERS; GAS;
D O I：
10.1039/d2cc06107d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient nickel-catalyzed cross-coupling for the synthesis of 2-sulfonylthiazoles from readily available 2-chlorobenzothiazoles and sodium sulfinates has been developed. A variety of 2-chlorobenzothiazoles and sulfinates having a diverse range of substitution patterns can undergo the coupling process successfully at room temperature. Avoiding the use of precious catalysts and sensitive ligands, moderate to excellent yields of various 2-sulfonylthiazoles were observed.
引用
收藏
页码：1050 / 1053
页数：4
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