Nickel-catalyzed sulfonylative coupling of 2-chlorobenzothiazoles with sulfinates at room temperature

被引：5

作者：

Zhu, Haibo ^{[1
]}

Zhang, Yingying ^{[1
]}

Ren, Gaowen ^{[1
]}

Wang, Yaoqi ^{[1
]}

Meng, Jia ^{[1
]}

Fan, Qiangwen ^{[1
]}

Xie, Zongbo ^{[1
]}

Le, Zhang-Gao ^{[1
]}

机构：

[1] East China Univ Technol, Jiangxi Prov Key Lab Synthet Chem, Nanchang 330013, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 08期

基金：

中国国家自然科学基金;

关键词：

SULFUR-DIOXIDE SURROGATE; O BOND ACTIVATION; ANTIMICROBIAL ACTIVITY; C-S; NI; CONSTRUCTION; SODIUM; ETHERS; GAS;

D O I：

10.1039/d2cc06107d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient nickel-catalyzed cross-coupling for the synthesis of 2-sulfonylthiazoles from readily available 2-chlorobenzothiazoles and sodium sulfinates has been developed. A variety of 2-chlorobenzothiazoles and sulfinates having a diverse range of substitution patterns can undergo the coupling process successfully at room temperature. Avoiding the use of precious catalysts and sensitive ligands, moderate to excellent yields of various 2-sulfonylthiazoles were observed.

引用

页码：1050 / 1053

页数：4

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